Formamidinium Thiocyanate CH₃N₃S 99% Powder ATOMFAIR®

$245.00

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Research grade formamidinium thiocyanate CH₃N₃S powder, >99% purity, 5 g pack, MW 89.14 g/mol for FA perovskite precursor solutions.

FORMAMIDINIUM THIOCYANATE CH₃N₃S 99% FASCN

RESEARCH GRADE MATERIAL

Product Overview

Formamidinium Thiocyanate (CH₃N₃S, FASCN) is a formamidinium-based perovskite precursor additive with CH₃N₃S 99% purity FASCN, supplied as a white powder with a molecular weight of 89.14 g/mol. This compound functions as an effective perovskite crystallization modulator, where the thiocyanate anion regulates crystal nucleation and growth kinetics during thin film formation. By retarding crystallization, FASCN promotes larger grain sizes and reduces internal film defect density, directly enhancing charge carrier mobility and power conversion efficiency in formamidinium-based perovskite solar cells. The material exhibits excellent solubility in polar organic solvents and water, enabling versatile precursor solution formulation across multiple deposition protocols. Widely utilized in university and research institute laboratories for photovoltaic device and photodetector experimental research, this high-purity additive is compatible with solution spin-coating and precursor solution blending preparation techniques. Strict light-sensitive hygroscopic dry storage is required to maintain material integrity.

Technical Specifications

PARAMETER DETAILS
Molecular Formula CH₃N₃S
Molecular Weight 89.14 g/mol
Specification 5 g
Purity >99%
Physical Form White Powder
Solubility Freely Soluble in Polar Organic Solvents and Water
Storage Conditions Light-Protected, Dry, Sealed, Room Temperature
Custom Configurations Other packaging specifications are available upon request. Please contact us via email for custom orders.

Key Features & Advantages

  • Thiocyanate-Mediated Crystallization Control for FA-Based Perovskites: The thiocyanate anion specifically modulates nucleation and growth kinetics in formamidinium-based perovskite systems, promoting larger grain sizes and reduced grain boundary density for enhanced charge transport compared to conventionally processed films.
  • Enhanced Carrier Mobility via Defect Density Reduction: By reducing internal film defect density through controlled crystallization, FASCN directly improves charge carrier mobility and suppresses non-radiative recombination, contributing to higher power conversion efficiency in completed photovoltaic devices.
  • Broad Solvent Compatibility for Versatile Processing: The compound is freely soluble in polar organic solvents and water, providing exceptional flexibility in precursor solution formulation across DMF, DMSO, and aqueous-based perovskite deposition protocols.
  • Ultra-High Purity Exceeding 99%: Refined to >99% purity with low batch impurity content, the additive introduces minimal extrinsic contamination during the crystallization modulation process, ensuring reproducible film quality across experimental batches.

APPLICATION SCOPE: Crystallization additive for formamidinium-based perovskite thin film preparation via spin-coating and solution blending. Grain size enhancement agent for reducing internal film defects and improving film morphology. Precursor solution additive for enhancing charge carrier mobility in FA-based perovskite solar cells. Compatible with one-step and two-step deposition protocols utilizing polar organic solvent systems. Supports photovoltaic device and photodetector research in university and research institute laboratories where controlled crystallization and defect reduction are experimental priorities.
PACKAGING: This listing is for the 5 g specification. Other packaging weights are available upon custom request. Each package is sealed under inert atmosphere within light-protective packaging to prevent photodegradation and moisture ingress. The hygroscopic nature of formamidinium thiocyanate necessitates immediate transfer to a desiccated, light-protected storage environment upon receipt. For bulk quantities or custom packaging specifications, please contact us via email.
IMPORTANT NOTICE: Formamidinium thiocyanate is hygroscopic and light-sensitive. Tighten the container cap immediately after each use to prevent moisture ingress from ambient air. Wear protective gloves throughout all experimental procedures to avoid direct skin contact. Store in a light-protected, moisture-free environment; do not store together with strong oxidizing agents or acidic reagents. Exposure to atmospheric moisture will cause deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry. When preparing precursor solutions, handle the white powder within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm). The compound is freely soluble in polar organic solvents and water. For detailed safety and handling information, consult the Safety Data Sheet prior to use.
TAILORED SOLUTIONS FOR RESEARCH
Contact our engineering team for technical support or official quotations.
EMAIL: inquiry@atomfair.com
Manufacturer: Atomfair LLC
Brand: ATOMFAIR®

This material is hygroscopic and light-sensitive, requiring storage in a light-protected, dry, sealed container at room temperature. Exposure to atmospheric moisture causes deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry.

  • Moisture Sensitivity: Immediate transfer to a desiccated, light-protected environment upon receipt is required to prevent moisture ingress.
  • Light Sensitivity: Light-protective packaging must be maintained to prevent photodegradation of the compound.
  • Inert Atmosphere Handling: Precursor solution preparation must be performed within an inert-atmosphere glovebox with H₂O < 1 ppm and O₂ < 1 ppm.
  • Container Integrity: The container cap must be tightened immediately after each use to prevent ambient moisture ingress.

This procedure describes the safe handling and precursor solution preparation of formamidinium thiocyanate under inert atmosphere. The material is hygroscopic and light-sensitive, requiring controlled conditions to maintain purity.

Required Equipment: Inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm), Light-protective storage container, Protective gloves

  1. Prepare Glovebox Environment
    Verify that the inert-atmosphere glovebox maintains H₂O < 1 ppm and O₂ < 1 ppm before introducing the material.
  2. Transfer Material to Glovebox
    Transfer the sealed, light-protective container into the glovebox antechamber and purge according to standard protocol.
  3. Weigh Required Amount
    Open the container inside the glovebox and weigh the required amount of white powder using a clean spatula.
  4. Prepare Precursor Solution
    Dissolve the weighed powder in the appropriate polar organic solvent (e.g., DMF or DMSO) under continuous stirring until fully dissolved.
  5. Reseal Container
    Tighten the container cap immediately after use to prevent moisture ingress from ambient air.

How does formamidinium thiocyanate (FASCN) improve perovskite solar cell efficiency?

FASCN acts as a crystallization modulator via the thiocyanate anion, which regulates nucleation and growth kinetics during thin film formation. This promotes larger grain sizes and reduces internal film defect density, directly enhancing charge carrier mobility and suppressing non-radiative recombination, leading to higher power conversion efficiency in formamidinium-based perovskite solar cells.

What solvent systems are compatible with FASCN for precursor solution formulation?

FASCN is freely soluble in polar organic solvents such as DMF and DMSO, as well as water, providing exceptional flexibility for precursor solution formulation. It is compatible with both one-step and two-step deposition protocols that utilize polar organic solvent systems, enabling versatile processing across multiple perovskite deposition methods.

What are the critical storage and handling requirements for FASCN to prevent degradation?

FASCN is hygroscopic and light-sensitive, requiring storage in a light-protected, dry, sealed container at room temperature. Handling must be performed in an inert-atmosphere glovebox with H₂O < 1 ppm and O₂ < 1 ppm to prevent deliquescence and hydrolysis. The container cap must be tightened immediately after each use, and the material should not be stored with strong oxidizing agents or acidic reagents.

Formamidinium Thiocyanate (FASCN) is a high-purity (>99%) perovskite crystallization modulator that enhances grain size and reduces defect density in FA-based perovskite films, but requires strict inert-atmosphere handling and light-protected dry storage to prevent moisture-induced degradation.

Positive

  • Thiocyanate-Mediated Crystallization Control: The thiocyanate anion modulates nucleation and growth kinetics in formamidinium-based perovskite systems, promoting larger grain sizes and reduced grain boundary density for enhanced charge transport compared to conventionally processed films.
  • Broad Solvent Compatibility: Freely soluble in polar organic solvents and water, providing exceptional flexibility in precursor solution formulation across DMF, DMSO, and aqueous-based perovskite deposition protocols.

Trade-offs

  • Hygroscopic and Light-Sensitive Storage Required: The compound is hygroscopic and light-sensitive; must be stored in a light-protected, dry, sealed environment at room temperature and handled within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm) to prevent degradation.
  • Moisture-Induced Irreversible Degradation: Exposure to atmospheric moisture causes deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry and compromising experimental reproducibility.

Every advanced material, component, equipment, and instrument in our catalog is backed by rigorous testing. We maintain strict internal quality management frameworks and align with CE conformity metrics to deliver transparent, reproducible performance data via our public open-science repository.

To request raw batch performance data, submit formal vendor registration paperwork, or execute a fast-turnaround R&D manufacturing loop, contact us at inquiry@atomfair.com.

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