n-Octylammonium Iodide OAI 99% 10 g Research Grade ATOMFAIR®

$158.00

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Research grade n-Octylammonium Iodide OAI, >99% purity, 10 g, CAS 60734-63-6, for 2D perovskite spacer and grain passivation. Order now.

N-OCTYLAMMONIUM IODIDE C₈H₂₀IN 99% OAI CAS 60734-63-6

RESEARCH GRADE MATERIAL

Product Overview

n-Octylammonium Iodide (C₈H₂₀IN, OAI, CAS 60734-63-6) is a long-alkyl-chain organic iodide salt with C₈H₂₀IN 99% purity OAI, supplied as a white powder with a molecular weight of 257.16 g/mol. This compound functions as a 2D layered perovskite spacer precursor, where the long octyl chain creates a steric barrier effect that passivates grain boundary defects in perovskite thin films while simultaneously blocking moisture penetration. The hydrophobic alkyl chain significantly enhances the environmental stability of perovskite optoelectronic devices by forming a protective organic layer between inorganic perovskite sheets. The material is widely utilized in university and research institute laboratories for two-dimensional perovskite solar cell, photodetector, and light-emitting device experimental research. Compatible with spin-coating and solution blending thin-film preparation techniques, this high-purity precursor requires strict light-sensitive hygroscopic dry storage to maintain material integrity.

Technical Specifications

PARAMETER DETAILS
Molecular Formula C₈H₂₀IN
CAS Number 60734-63-6
Molecular Weight 257.16 g/mol
Specification 10 g
Purity >99%
Physical Form White Powder
Storage Conditions Light-Protected, Dry, Sealed, Room Temperature
Custom Configurations Other packaging specifications are available upon request. Please contact us via email for custom orders.

Key Features & Advantages

  • Long Alkyl Chain Steric Barrier for Moisture Resistance: The eight-carbon octyl chain provides a hydrophobic steric barrier that effectively blocks moisture penetration into the perovskite lattice, significantly enhancing environmental stability compared to short-chain or aromatic ammonium counterparts.
  • Effective 2D Layered Perovskite Spacer Cation: OAI serves as the organic spacer layer in Ruddlesden-Popper phase two-dimensional perovskites, where the long alkylammonium cation templates the formation of quantum-well structures with enhanced exciton binding energy and tunable optoelectronic properties.
  • Grain Boundary Passivation via Steric Hindrance: The bulky octylammonium cation selectively occupies grain boundary sites in mixed 2D/3D perovskite films, passivating defect states through steric hindrance while forming a moisture-blocking organic network at perovskite film surfaces.
  • Ultra-High Purity Exceeding 99%: Refined to >99% purity with low batch impurity content, the precursor minimizes extrinsic defects in 2D perovskite thin films and supports reproducible device performance across experimental batches.

APPLICATION SCOPE: Organic spacer cation for 2D Ruddlesden-Popper phase layered perovskite synthesis. Grain boundary passivation agent for mixed 2D/3D perovskite thin films in high-stability solar cells. Moisture barrier precursor for environmentally stable perovskite optoelectronic devices. Compatible with spin-coating and solution blending deposition protocols. Supports two-dimensional perovskite solar cell, photodetector, and light-emitting device research in university and research institute laboratories where enhanced environmental stability is a primary experimental objective.
PACKAGING: This listing is for the 10 g specification. Other packaging weights are available upon custom request. Each package is sealed under inert atmosphere within light-protective packaging to prevent photodegradation and moisture ingress. The hygroscopic nature of n-octylammonium iodide necessitates immediate transfer to a desiccated, light-protected storage environment upon receipt. For bulk quantities or custom packaging specifications, please contact us via email.
IMPORTANT NOTICE: n-Octylammonium iodide is hygroscopic and light-sensitive. Tighten the container cap immediately after each use to prevent moisture ingress from ambient air. Wear protective gloves throughout all experimental procedures to avoid direct skin contact. Store in a light-protected, moisture-free environment; do not store together with strong oxidizing agents or acidic reagents. Exposure to atmospheric moisture will cause deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry. When preparing precursor solutions, handle the white powder within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm). For detailed safety and handling information, consult the Safety Data Sheet prior to use.
TAILORED SOLUTIONS FOR RESEARCH
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EMAIL: inquiry@atomfair.com
Manufacturer: Atomfair LLC
Brand: ATOMFAIR®

This material is hygroscopic and light-sensitive, requiring strict protection from moisture and light to prevent irreversible degradation. Storage must be in a sealed, dry, light-protected environment at room temperature, with inert-atmosphere handling during solution preparation.

  • Moisture Sensitivity: Exposure to atmospheric moisture causes deliquescence and hydrolysis, irreversibly altering the precursor stoichiometry.
  • Light Sensitivity: Photodegradation occurs upon prolonged exposure to light, necessitating light-protective packaging and storage.
  • Handling Atmosphere: Precursor solution preparation must be performed in an inert-atmosphere glovebox with H₂O and O₂ levels below 1 ppm to prevent moisture ingress.
  • Incompatible Materials: Strong oxidizing agents and acidic reagents must be avoided during storage and handling to prevent hazardous reactions.
  • Post-Use Sealing: The container cap must be tightened immediately after each use to prevent ambient moisture from entering the container.

This procedure ensures the material remains dry and protected from light during storage and use. Proper handling prevents moisture-induced degradation and maintains purity for reproducible perovskite device fabrication.

Required Equipment: Inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm), Light-protective, desiccated storage container, Chemical-resistant gloves

  1. Transfer to Storage
    Inspect the sealed package upon receipt and immediately transfer the container to a desiccated, light-protected storage cabinet at room temperature.
  2. Prepare Handling Environment
    Confirm the glovebox atmosphere is below 1 ppm H₂O and 1 ppm O₂ before opening the container for solution preparation.
  3. Weigh and Dispense
    Wear gloves and dispense the required amount of white powder inside the glovebox, minimizing exposure to ambient light by working quickly.
  4. Reseal Container
    Tighten the container cap immediately after use and return the container to the desiccated, light-protected storage environment.

Why is the long alkyl chain (C8) specifically advantageous for moisture resistance compared to shorter chain ammonium halides?

The eight-carbon octyl chain provides a hydrophobic steric barrier that effectively blocks moisture penetration into the perovskite lattice, significantly enhancing environmental stability compared to short-chain or aromatic ammonium counterparts. This steric effect is a key advantage for 2D layered perovskite devices requiring long-term operational stability.

What are the critical handling requirements when using n-Octylammonium Iodide as a 2D perovskite spacer precursor?

n-Octylammonium Iodide is hygroscopic and light-sensitive. It must be stored in a light-protected, dry, sealed container at room temperature. For solution preparation, handling should be performed in an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm) to prevent deliquescence and hydrolysis that would irreversibly degrade precursor stoichiometry. The container cap must be tightened immediately after each use.

How does the >99% purity level of OAI impact device reproducibility in 2D/3D perovskite solar cells?

The >99% purity minimizes extrinsic defects in 2D perovskite thin films, supporting reproducible device performance across experimental batches. Low batch impurity content ensures consistent grain boundary passivation and moisture barrier formation, which is critical for reliable comparison of device efficiencies in research settings.

n-Octylammonium Iodide (OAI) is a high-purity (>99%) organic iodide salt designed as a 2D layered perovskite spacer cation, where the long octyl chain provides a hydrophobic steric barrier that enhances moisture resistance and passivates grain boundary defects in perovskite thin films. Its hygroscopic and light-sensitive nature mandates strict inert-atmosphere handling and desiccated storage to prevent degradation.

Positive

  • Long alkyl chain moisture barrier: The eight-carbon octyl chain provides a hydrophobic steric barrier that blocks moisture penetration into the perovskite lattice, significantly enhancing environmental stability compared to short-chain or aromatic ammonium counterparts.
  • Ultra-high purity >99%: Refined to >99% purity with low batch impurity content, the precursor minimizes extrinsic defects in 2D perovskite thin films and supports reproducible device performance across experimental batches.

Trade-offs

  • Hygroscopic and light-sensitive storage: The material is hygroscopic and light-sensitive; exposure to atmospheric moisture causes deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry. Requires immediate transfer to a desiccated, light-protected environment upon receipt.
  • Inert-atmosphere handling required: When preparing precursor solutions, the white powder must be handled within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm) to prevent moisture ingress and maintain material integrity.

Every advanced material, component, equipment, and instrument in our catalog is backed by rigorous testing. We maintain strict internal quality management frameworks and align with CE conformity metrics to deliver transparent, reproducible performance data via our public open-science repository.

To request raw batch performance data, submit formal vendor registration paperwork, or execute a fast-turnaround R&D manufacturing loop, contact us at inquiry@atomfair.com.

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