Methylammonium Iodide MAI >99% CAS 14965-49-2

$120.00

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Research-grade CH3NH3I MAI >99% purity, 10 g white crystalline perovskite precursor, CAS 14965-49-2, MW 159.5 g/mol; dry light-protected storage. Order now.

Description

METHYLAMMONIUM IODIDE CH₃NH₃I 99% MAI CAS 14965-49-2

RESEARCH GRADE MATERIAL

Product Overview

Methylammonium Iodide (CH₃NH₃I, MAI, CAS 14965-49-2) is a core iodine-based perovskite solar cell precursor with CH₃NH₃I 99% purity MAI, supplied as a white crystalline solid with a molecular weight of 159.5 g/mol. This high-purity organohalide salt serves as the fundamental precursor for MAPbI₃, FAPbI₃, and mixed-cation cesium-containing composite perovskite solution formulations. The material exhibits excellent solubility in water, N,N-dimethylformamide, and dimethyl sulfoxide, with additional solubility in methanol and isopropanol, enabling versatile precursor preparation across multiple deposition protocols. Widely utilized in laboratory perovskite thin film preparation, optoelectronic device fabrication, and photodetector research, this high-purity precursor is compatible with spin-coating, vacuum thermal evaporation, and solution-based synthetic techniques. Due to its strongly hygroscopic nature, the product requires strict light-sensitive hygroscopic dry storage—sealed under inert atmosphere, protected from light, and maintained at room temperature—to preserve stoichiometric integrity prior to precursor solution preparation.

Technical Specifications

PARAMETER DETAILS
Model OPV-CH₃NH₃I
Molecular Formula CH₃NH₃I
CAS Number 14965-49-2
Molecular Weight 159.5 g/mol
Specification 10 g
Purity >99%
Physical Form White Crystalline Solid
Solubility Freely Soluble in Water, DMF, DMSO; Soluble in Methanol, Isopropanol
Storage Conditions Light-Protected, Dry, Sealed, Room Temperature
Custom Configurations Other packaging specifications are available upon request. Please contact us via email for custom orders.

Key Features & Advantages

  • Fundamental Precursor for Hybrid Perovskite Formulations: MAI serves as the core iodine source for MAPbI₃, mixed-cation FA/MA, and cesium-containing composite perovskite solutions, making it the essential starting material for virtually all hybrid perovskite thin film research.
  • Broad Solvent Compatibility for Versatile Processing: Excellent solubility in water, N,N-dimethylformamide, and dimethyl sulfoxide, with additional solubility in methanol and isopropanol, enables flexible precursor solution formulation across spin-coating, vacuum evaporation, and solution-based synthetic routes.
  • Defined Molecular Weight for Precise Stoichiometry: With a molecular weight of 159.5 g/mol, the precursor supports accurate molar calculations for MAPbI₃ and mixed-cation mixed-halide perovskite formulations, essential for bandgap engineering and compositional optimization studies.
  • Ultra-High Purity Exceeding 99%: Refined to >99% purity with low batch impurity content, the precursor minimizes extrinsic ionic defects in perovskite thin films and supports reproducible device performance across multiple deposition techniques.

APPLICATION SCOPE: Primary iodine source for MAPbI₃ and mixed-cation FA/MA/Cs perovskite light-absorbing layer synthesis. Essential precursor for FAPbI₃ and FA/Cs composite perovskite solution formulations. Compatible with one-step spin-coating, two-step sequential deposition, vacuum thermal evaporation, and solution-based synthetic protocols. Supports perovskite thin film preparation, optoelectronic device fabrication, and photodetector research in university and research institute laboratories.
PACKAGING: This listing is for the 10 g specification. Other packaging weights are available upon custom request. Each package is sealed under inert atmosphere within light-protective packaging to prevent photodegradation and moisture ingress. The strongly hygroscopic nature of methylammonium iodide necessitates immediate transfer to a desiccated, light-protected storage environment upon receipt. For bulk quantities or custom packaging specifications, please contact us via email.
IMPORTANT NOTICE: Methylammonium iodide is strongly hygroscopic and light-sensitive. Tighten the container cap immediately after each use to prevent moisture ingress from ambient air. Wear protective gloves throughout all experimental procedures to avoid direct skin contact. Store in a light-protected, moisture-free environment; do not store together with strong oxidizing agents or strong acids. Exposure to atmospheric moisture will cause deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry. When preparing precursor solutions, handle the white crystalline solid within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm). The compound is freely soluble in water, DMF, and DMSO, and soluble in methanol and isopropanol. For detailed safety and handling information, consult the Safety Data Sheet prior to use.
TAILORED SOLUTIONS FOR RESEARCH
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Manufacturer: Atomfair LLC
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This compound is strongly hygroscopic and light-sensitive, requiring storage under inert atmosphere and light protection. Exposure to atmospheric moisture causes deliquescence and irreversible stoichiometric degradation.

  • Inert Atmosphere Storage: Seal the container under inert atmosphere and store at room temperature in a light-protected environment to prevent moisture ingress and photodegradation.
  • Glovebox Requirement for Solution Preparation: Handle the solid inside an inert-atmosphere glovebox with H₂O < 1 ppm and O₂ < 1 ppm when preparing precursor solutions.
  • Incompatibility with Oxidizers and Acids: Do not store together with strong oxidizing agents or strong acids to avoid hazardous reactions.
  • Immediate Post-Receipt Handling: Upon receipt, transfer the package to a desiccated, light-protected storage environment to maintain stoichiometric integrity.

This protocol ensures the integrity of hygroscopic methylammonium iodide during storage and solution formulation. Strict inert atmosphere and light protection are required to avoid decomposition.

Required Equipment: Inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm)

  1. Transfer to Storage
    Upon receipt, transfer the sealed package to a desiccated, light-protected storage environment to prevent moisture uptake.
  2. Prepare Glovebox Environment
    Ensure the inert-atmosphere glovebox is active with H₂O < 1 ppm and O₂ < 1 ppm before introducing the material.
  3. Weigh Precursor Inside Glovebox
    Transfer the white crystalline solid into a clean vial within the glovebox, using a spatula, and cap immediately to avoid moisture exposure.
  4. Dissolve in Anhydrous Solvent
    Add the required volume of anhydrous DMF or DMSO to the solid and mix until fully dissolved, maintaining the solution inside the glovebox.
  5. Post-Use Container Closure
    Tighten the original container cap immediately after each use to prevent ambient moisture from entering the bulk material.

How does the >99% purity of methylammonium iodide influence ionic defect formation and reproducibility in perovskite thin films?

The >99% purity minimizes extrinsic ionic defects in perovskite thin films by reducing batch impurity content, directly supporting reproducible device performance across multiple deposition techniques. This is critical for bandgap engineering and compositional optimization studies relying on precise stoichiometry with the defined molecular weight of 159.5 g/mol.

Is methylammonium iodide compatible with both one-step spin-coating and vacuum thermal evaporation for perovskite solar cell fabrication?

Yes, it is compatible with one-step spin-coating, two-step sequential deposition, vacuum thermal evaporation, and solution-based synthetic protocols. Its broad solubility in water, DMF, DMSO, methanol, and isopropanol enables flexible precursor solution formulation across these techniques.

What specific storage and handling infrastructure is required for methylammonium iodide to prevent stoichiometric degradation?

The compound is strongly hygroscopic and light-sensitive, requiring sealed inert atmosphere, light-protected packaging, and room temperature storage. For handling, use an inert-atmosphere glovebox with H2O < 1 ppm and O2 < 1 ppm, and transfer immediately to a desiccated, light-protected environment upon receipt to prevent deliquescence and hydrolysis.

Methylammonium Iodide (MAI) is a high-purity perovskite precursor offering excellent solvent compatibility for versatile deposition, but requires strict inert-atmosphere handling and immediate dry storage to prevent moisture-induced degradation.

Positive

  • Ultra-High Purity >99% for Reproducible Devices: Refined to >99% purity with low batch impurity content, minimizing extrinsic ionic defects in perovskite thin films and supporting reproducible device performance across multiple deposition techniques.
  • Broad Solvent Compatibility Enables Flexible Processing: Freely soluble in water, DMF, and DMSO, with additional solubility in methanol and isopropanol, enabling versatile precursor formulation for spin-coating, vacuum evaporation, and solution-based deposition routes.

Trade-offs

  • Requires Inert-Atmosphere Glovebox Handling: The strongly hygroscopic nature demands handling within an inert-atmosphere glovebox (H2O < 1 ppm, O2 < 1 ppm) to prevent moisture-induced deliquescence and stoichiometric degradation.
  • Strong Hygroscopicity Needs Immediate Dry Storage: Upon receipt, the material must be transferred to a desiccated, light-protected environment to avoid moisture ingress, which irreversibly hydrolyzes the precursor and degrades performance.

Every advanced material, component, equipment, and instrument in our catalog is backed by rigorous testing. We maintain strict internal quality management frameworks and align with CE conformity metrics to deliver transparent, reproducible performance data via our public open-science repository.

To request raw batch performance data, submit formal vendor registration paperwork, or execute a fast-turnaround R&D manufacturing loop, contact us at inquiry@atomfair.com.

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