Formamidinium Chloride FACl 99.99% 10 g Powder

$169.00

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Research grade FACl powder, CH5ClN2, CAS 6313-33-3, >99.99% purity in 10 g pack for perovskite lattice modulation and grain passivation. Order now.

Description

FORMAMIDINIUM CHLORIDE CH₅CLN₂ 99.99% FACL CAS 6313-33-3

RESEARCH GRADE MATERIAL

Product Overview

Formamidinium Chloride (CH₅ClN₂, FACl, CAS 6313-33-3) is a chlorine-based formamidinium perovskite precursor with CH₅ClN₂ 99.99% purity FACl, supplied as a white powder with a molecular weight of 80.52 g/mol and soluble in ethanol. This ultra-high-purity organohalide salt functions as a perovskite lattice modulation precursor, where chloride ions are introduced to regulate the perovskite crystal lattice structure, modulate material bandgap, and simultaneously passivate grain boundary defects in the resulting thin film. The chloride incorporation improves charge carrier transport efficiency by reducing trap-mediated recombination pathways. Primarily employed in formamidinium-based hybrid perovskite thin film preparation, this ultra-high-purity grade with extremely low impurity content is suitable for photovoltaic cell, photodetector, and photocatalytic device research in university and research institute laboratories. Compatible with spin-coating and precursor solution blending thin-film preparation techniques, the product requires strict light-sensitive hygroscopic dry storage to maintain stoichiometric integrity.

Technical Specifications

PARAMETER DETAILS
Molecular Formula CH₅ClN₂
CAS Number 6313-33-3
Molecular Weight 80.52 g/mol
Specification 10 g
Purity >99.99%
Physical Form White Powder
Solubility Soluble in Ethanol
Storage Conditions Light-Protected, Dry, Sealed, Room Temperature
Custom Configurations Other packaging specifications are available upon request. Please contact us via email for custom orders.

Key Features & Advantages

  • Ultra-High Purity Exceeding 99.99%: The formamidinium chloride is refined to >99.99% purity with extremely low batch impurity content, making it suitable for applications requiring the highest levels of precursor purity where even trace contaminants compromise device performance and experimental reproducibility.
  • Chloride-Mediated Lattice and Bandgap Modulation: Chloride ion incorporation into formamidinium-based perovskite lattices enables controlled modification of crystal structure parameters and electronic bandgap, providing an additional dimension of compositional engineering for optimized device performance.
  • Dual Function: Grain Boundary Passivation with Carrier Transport Enhancement: FACl simultaneously passivates grain boundary defects while improving charge carrier transport efficiency, reducing trap-mediated recombination without compromising inter-grain electrical connectivity.
  • Ethanol Solubility for Processing Flexibility: The compound’s solubility in ethanol provides an alternative solvent pathway for precursor solution formulation, complementing conventional DMF- and DMSO-based processing protocols.

APPLICATION SCOPE: Chlorine source for formamidinium-based mixed-halide perovskite thin film preparation. Lattice structure modulator for FA-based perovskite compositional engineering. Grain boundary passivation additive for reducing trap-mediated recombination in perovskite solar cells. Bandgap tuning precursor through chloride incorporation in mixed-halide formulations. Compatible with spin-coating and precursor solution blending deposition protocols. Supports photovoltaic cell, photodetector, and photocatalytic device research in university and research institute laboratories.
PACKAGING: This listing is for the 10 g specification. Other packaging weights are available upon custom request. Each package is sealed under inert atmosphere within light-protective packaging to prevent photodegradation and moisture ingress. The strongly hygroscopic nature of formamidinium chloride necessitates immediate transfer to a desiccated, light-protected storage environment upon receipt. For bulk quantities or custom packaging specifications, please contact us via email.
IMPORTANT NOTICE: Formamidinium chloride is strongly hygroscopic and light-sensitive. Tighten the container cap immediately after each use to prevent moisture ingress from ambient air. Wear protective gloves throughout all experimental procedures to avoid direct skin contact. Store in a light-protected, moisture-free environment; do not store together with strong oxidizing agents or alkaline reagents. Exposure to atmospheric moisture will cause deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry. When preparing precursor solutions, handle the white powder within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm). The compound is soluble in ethanol. For detailed safety and handling information, consult the Safety Data Sheet prior to use.
TAILORED SOLUTIONS FOR RESEARCH
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EMAIL: inquiry@atomfair.com
Manufacturer: Atomfair LLC
Brand: ATOMFAIR®

Formamidinium chloride is strongly hygroscopic and light-sensitive, requiring strict environmental control to prevent degradation. Exposure to moisture causes irreversible hydrolysis and stoichiometric loss, while light exposure induces photodegradation.

  • Light-Sensitive Degradation: Exposure to light causes photodegradation of the compound, necessitating strict light-protective storage.
  • Hygroscopic Deliquescence: Atmospheric moisture absorption leads to deliquescence and hydrolysis, irreversibly degrading precursor stoichiometry.
  • Inert Atmosphere Requirement: All handling and solution preparation must be performed in an inert-atmosphere glovebox with H2O < 1 ppm and O2 < 1 ppm.
  • Storage Condition Requirements: Store in a sealed, light-protected, dry environment at room temperature, away from strong oxidizing agents and alkaline reagents.
  • Immediate Transfer After Receipt: Upon receipt, transfer the package immediately to a desiccated, light-protected storage environment to prevent moisture ingress.

This procedure outlines safe handling and precursor solution preparation for formamidinium chloride. All steps must be performed under inert atmosphere to maintain compound integrity.

Required Equipment: Inert-atmosphere glovebox, Light-protective storage container, Desiccator

  1. Receive and Store
    Transfer the sealed package immediately to a desiccated, light-protected storage environment upon receipt.
  2. Don Protective Gloves
    Wear protective gloves before handling the compound to avoid direct skin contact.
  3. Access in Glovebox
    Place the container inside an inert-atmosphere glovebox with moisture and oxygen levels below 1 ppm before opening.
  4. Dispense Powder
    Open the container only inside the glovebox and dispense the required amount of powder using a clean spatula.
  5. Reseal Container
    Tighten the container cap immediately after dispensing to prevent moisture ingress into the remaining powder.
  6. Prepare Precursor Solution
    Dissolve the formamidinium chloride powder in ethanol to prepare the precursor solution for thin-film deposition.

What trade-off exists between the bandgap modulation benefits of using Formamidinium Chloride and the stringent handling requirements?

The chloride ion incorporation in Formamidinium Chloride enables precise bandgap tuning and defect passivation, improving charge carrier transport efficiency. However, the compound is strongly hygroscopic and light-sensitive, requiring strict inert-atmosphere glovebox handling (H₂O < 1 ppm, O₂ < 1 ppm) and light-protected, dry storage to prevent deliquescence and hydrolysis that would irreversibly degrade precursor stoichiometry.

Can Formamidinium Chloride be integrated into conventional DMF- or DMSO-based perovskite precursor solutions?

Yes, Formamidinium Chloride is soluble in ethanol and provides an alternative solvent pathway that complements conventional DMF- and DMSO-based processing protocols. Its compatibility with spin-coating and precursor solution blending makes it suitable for direct integration into standard formamidinium-based hybrid perovskite thin film preparation workflows.

What are the critical storage and handling requirements for Formamidinium Chloride to prevent degradation?

Formamidinium Chloride requires light-protected, dry, sealed storage at room temperature. It is strongly hygroscopic and must be handled within an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm). The container cap must be tightened immediately after use to prevent moisture ingress, and the powder should be transferred to a desiccated, light-protected environment upon receipt.

Formamidinium Chloride (FACl) 99.99% is an ultra-high-purity perovskite precursor offering chloride-mediated lattice modulation and grain boundary passivation, but requires strict inert-atmosphere handling and light-protected hygroscopic storage to maintain stoichiometric integrity.

Positive

  • Ultra-High Purity >99.99%: Refined to >99.99% with extremely low batch impurity content, ensuring minimal contamination for reproducible device performance in photovoltaic and photodetector research.
  • Dual Passivation and Carrier Enhancement: Simultaneously passivates grain boundary defects and improves charge carrier transport efficiency by reducing trap-mediated recombination, enhancing device performance without compromising inter-grain connectivity.

Trade-offs

  • Strict Light-Sensitive Hygroscopic Storage: Strongly hygroscopic and light-sensitive; requires immediate transfer to a desiccated, light-protected environment and immediate cap tightening after each use to prevent deliquescence and hydrolysis.
  • Inert-Atmosphere Handling Required: Powder must be handled inside an inert-atmosphere glovebox (H₂O < 1 ppm, O₂ < 1 ppm) when preparing precursor solutions to avoid moisture-induced degradation and maintain stoichiometric integrity.

Every advanced material, component, equipment, and instrument in our catalog is backed by rigorous testing. We maintain strict internal quality management frameworks and align with CE conformity metrics to deliver transparent, reproducible performance data via our public open-science repository.

To request raw batch performance data, submit formal vendor registration paperwork, or execute a fast-turnaround R&D manufacturing loop, contact us at inquiry@atomfair.com.

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