Description
Key Properties & Advantages
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Cobalt-Driven Activity: Cobalt nodes provide Lewis acid sites and redox activity, enhancing catalytic performance in reduction/oxidation reactions and enabling electroactive behavior in energy devices.
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High Porosity & Surface Area: Features a well-defined porous network with a large BET surface area (typically 1200–1600 m²/g) and uniform pore size (~1.1 nm), facilitating efficient molecular diffusion, adsorption, and catalytic site accessibility.
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Exceptional Chemical Stability: Exhibits robust stability in aqueous and organic environments (pH 3–11) and moderate thermal resistance (up to 300°C under inert conditions), outperforming many MOFs in practical operational settings.
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Processability: Easily fabricated into powders, thin films, or composites with other materials (e.g., cement, polymers, substrates), expanding its applicability across industries.
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Tunable Functionality: Retains structural integrity during post-synthetic modification (e.g., metal doping, ligand functionalization), allowing customization for target applications.
Core Applications
Biosensing & Disease Diagnosis
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Enhances catalytic and electrocatalytic signals in biosensors, enabling sensitive detection of biomolecules (e.g., biomarkers, pathogens) via amplified electrochemical or optical responses.
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Its porous structure can encapsulate recognition elements (e.g., antibodies, enzymes), improving specificity in diagnostic assays.
Cement Composites
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Improves compressive strength by reinforcing the cement matrix and reducing porosity through controlled particle dispersion.
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Refines microstructure by facilitating more uniform hydration of cement particles, enhancing durability and resistance to cracking.
NOₓ Selective Reduction Catalysis
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Exhibits high activity for selective catalytic reduction (SCR) of NOₓ using CO as a reducing agent, even under oxygen-rich conditions (mimicking industrial flue gas environments).
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Cobalt nodes act as active sites for NOₓ adsorption and activation, promoting efficient conversion to N₂ and CO₂.
Photocatalytic CO₂ Reduction
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Demonstrates exceptional performance in reducing CO₂ to CO under light irradiation, with high CO production yields attributed to cobalt’s redox activity and the framework’s ability to concentrate CO₂ molecules.
Supercapacitor Thin Films
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Display robust electrochemical performance, including high specific capacitance, excellent cycling stability (≥10,000 cycles), and rapid charge-discharge rates.
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The cobalt-based framework enables pseudocapacitive behavior, complementing the electric double-layer capacitance of porous carbon substrates for enhanced energy storage.
Technical Specifications
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Parameter
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Details
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Chemical Composition
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Cobalt(II) 2-methylimidazolate (Co(C₄H₄N₂)₂)
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Appearance
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Purple crystalline powder (thin films: uniform purple coatings)
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BET Surface Area
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1200–1600 m²/g
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Pore Size
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~1.1 nm (uniform microporous network)
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Thermal Stability
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Up to 300°C (inert atmosphere); stable up to 200°C in air
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Chemical Stability
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Stable in water (pH 3–11) and organic solvents (e.g., methanol, ethanol, DMF)
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Quality Assurance
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X-ray diffraction (XRD) confirms zeolitic topology and crystallinity.
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Nitrogen adsorption-desorption analysis verifies surface area and pore size distribution.
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Scanning electron microscopy (SEM) ensures uniform particle morphology (powders) or film coverage (thin films).
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Catalytic activity testing (for selected batches) validates functionality in model reactions (e.g., CO oxidation).
Packaging & Storage
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Storage: Store at room temperature in a dry environment. Avoid prolonged exposure to strong acids or reducing agents to preserve structural integrity. Shelf life is ≥12 months under proper storage conditions.

