Description
Key Properties & Advantages
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Erbium-Driven Electronic Properties: Erbium’s unique 4f electronic configuration endows the material with exceptional near-infrared (NIR) luminescence (emission typically in 1500–1600 nm range) and strong Lewis acidity—properties rarely combined in traditional MOFs.
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High Surface Area & Tunable Porosity: Retains the hallmark MOF advantages of large BET surface area (typically 500–900 m²/g) and adjustable pore size (0.8–2.0 nm), enabling efficient molecular adsorption, catalytic site accessibility, and guest-host interactions.
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Rare-Earth Photophysical Traits: Erbium’s NIR luminescence is less susceptible to autofluorescence and tissue scattering, making it valuable for bioimaging and optical sensing applications. Its long luminescence lifetime (μs-ms scale) enhances signal-to-noise ratios in detection.
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Lewis Acid Catalytic Activity: Erbium nodes act as robust Lewis acid sites, promoting reactivity in asymmetric catalysis (e.g., enantioselective synthesis) and organic transformations (e.g., cycloadditions, esterifications).
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Superior Crystallinity & Consistency: Precise synthesis controls ensure high crystallinity, which stabilizes luminescent properties and catalytic activity. Strict quality checks guarantee minimal batch variation in particle size, porosity, and erbium loading.
Applications
Near-Infrared Luminescence
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Bioimaging & Sensing: Erbium’s NIR emission (1530–1550 nm) penetrates deeply into biological tissues with minimal interference, enabling non-invasive in vivo imaging. It also serves as a luminescent probe for biomolecule detection (e.g., proteins, nucleic acids) via guest-induced luminescence quenching/enhancement.
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Optical Devices: Potential use in NIR lasers, amplifiers, and optical communication components, leveraging its stable luminescent output under excitation.
Asymmetric Catalysis
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Enantioselective Synthesis: Erbium’s Lewis acidity, combined with the MOF’s chiral framework (when using chiral ligands), promotes asymmetric reactions such as Diels-Alder cycloadditions and hydrogenations, achieving high enantiomeric excess (ee) values.
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Organic Transformation Catalysis: Efficiently catalyzes acid-mediated reactions (e.g., alcohol dehydration, acetalization) with high turnover numbers, thanks to the MOF’s porous structure that stabilizes active sites and facilitates substrate diffusion.
Environmental Pollutant Detection
Selective Gas Adsorption
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Rare Gas Separation: Erbium’s polarizability enables selective adsorption of noble gases (e.g., Xe, Kr) from gas mixtures, useful for nuclear waste treatment or rare gas purification.
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Small Molecule Capture: Tunable porosity and erbium-guest interactions enhance selectivity for gases like CO₂ and H₂, supporting carbon capture and hydrogen storage applications.
Technical Specifications
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Parameter
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Details
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Metal Node
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Erbium (Er³⁺)
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Ligand System
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Typically carboxylate-based (e.g., terephthalate derivatives) or β-diketonate ligands (tailored for luminescence/catalysis)
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Appearance
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Pale pink to off-white crystalline powder
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Crystallinity
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High (confirmed by XRD with sharp diffraction peaks)
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BET Surface Area
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500–900 m²/g
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Pore Size
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0.8–2.0 nm (tunable via ligand selection)
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Luminescence Range
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1500–1600 nm (NIR) under 980 nm excitation
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Purity
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≥95% (research grade, with trace metal impurities <0.1%)
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Quality Assurance
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X-ray diffraction (XRD) to verify crystallinity and phase purity.
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N₂ adsorption-desorption analysis to confirm surface area and pore size distribution.
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Photoluminescence spectroscopy (PL) to validate NIR emission intensity and lifetime.
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Inductively coupled plasma mass spectrometry (ICP-MS) to quantify erbium loading and impurity levels.
Packaging & Storage
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Available in 1g, 5g, and 10g quantities, packaged in airtight, light-resistant containers to protect luminescent properties. Store at room temperature in a dry, inert atmosphere (e.g., argon) to prevent moisture-induced degradation. Shelf life is ≥6 months under proper storage conditions.

