Description

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride (CAS No. 36309-88-3) is a highly specialized coordination complex featuring a ruthenium(II) center chelated by three 4,7-diphenyl-1,10-phenanthroline ligands, with two chloride counterions for charge balance. This compound is characterized by its molecular formula C₇₂H₄₈Cl₂N₆Ru and exhibits unique photophysical and electrochemical properties due to its extended aromatic system and metal-ligand charge transfer (MLCT) transitions. The rigid phenanthroline backbone, coupled with phenyl substituents, enhances its stability and luminescence efficiency, making it invaluable in advanced materials research. Suitable for use in organic electronics, sensing, and catalysis, this high-purity compound is rigorously tested for consistency and performance. Packaged under inert conditions to ensure long-term stability.

Properties

• CAS Number: 36309-88-3
• Complexity: 409
• IUPAC Name: 4,7-diphenyl-1,10-phenanthroline;ruthenium(2+);dichloride
• InChI: InChI=1S/3C24H16N2.2ClH.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;;;/h3*1-16H;2*1H;/q;;;;;+2/p-2
• InChI Key: SKZWFYFFTOHWQP-UHFFFAOYSA-L
• Exact Mass: 1168.236091
• Molecular Formula: C72H48Cl2N6Ru
• Molecular Weight: 1169.2
• SMILES: C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.[Cl-].[Cl-].[Ru+2]
• Topological: 77.3
• Monoisotopic Mass: 1168.236091
• Synonyms: 36309-88-3, tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(ii) dichloride, TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM (II) DICHLORIDE, 4,7-diphenyl-1,10-phenanthroline;ruthenium(2+);dichloride, tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(ii)dichloride, MFCD03095387, CID 11980975, SCHEMBL345453, SKZWFYFFTOHWQP-UHFFFAOYSA-L, AT26877, DA-68356, SY100624, A900992, Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium dichloride

Application

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride is widely employed as a phosphorescent dopant in organic light-emitting diodes (OLEDs) due to its efficient red-emitting properties. Its strong MLCT absorption bands make it a candidate for dye-sensitized solar cells (DSSCs) and photocatalytic applications. Researchers also utilize it as an electrochemical luminescence (ECL) probe in bioanalytical assays. The compound’s stability and tunable redox behavior are leveraged in supramolecular chemistry and molecular electronics.

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