Description
Tris([2,2′-bipyridine]-4,4′-diamine)ruthenium(II)dichloride (CAS No. 146082-65-7) is a high-purity ruthenium-based coordination complex with the molecular formula C30H30Cl2N12Ru. This compound features a central ruthenium(II) ion coordinated to three [2,2′-bipyridine]-4,4′-diamine ligands, forming a highly stable octahedral complex. Its unique structure and redox-active properties make it an excellent candidate for electrochemical and photochemical applications. The presence of amine-functionalized bipyridine ligands enhances its solubility in polar solvents and facilitates further functionalization for tailored research needs. This product is meticulously synthesized and purified to ensure >98% purity (HPLC), as confirmed by NMR and mass spectrometry. Ideal for researchers in materials science, catalysis, and molecular electronics, it is supplied as a dark red to brown crystalline powder, packaged under inert gas to ensure long-term stability. Store in a cool, dry place, protected from light and moisture.
Properties
- CAS Number: 146082-65-7
- Complexity: 597
- IUPAC Name: 2-(4-amino-2-pyridyl)pyridin-4-amine;ruthenium(2+);dichloride
- InChI: InChI=1S/3C10H10N4.2ClH.Ru/c3*11-7-1-3-13-9(5-7)10-6-8(12)2-4-14-10;;;/h3*1-6H,(H2,11,13)(H2,12,14);2*1H;/q;;;;;+2/p-2
- InChI Key: WDDFPDQNZGPCTG-UHFFFAOYSA-L
- Exact Mass: 730.113685
- Molecular Formula: C30H30Cl2N12Ru
- Molecular Weight: 730.6
- SMILES: C1=CN=C(C=C1N)C2=NC=CC(=C2)N.C1=CN=C(C=C1N)C2=NC=CC(=C2)N.C1=CN=C(C=C1N)C2=NC=CC(=C2)N.[Cl-].[Cl-].[Ru+2]
- Topological: 233
- Monoisotopic Mass: 730.113685
- Synonyms: Tris([2,2′-bipyridine]-4,4′-diamine)ruthenium(II)dichloride, 146082-65-7
Application
Tris([2,2′-bipyridine]-4,4′-diamine)ruthenium(II)dichloride is widely used as a photosensitizer in dye-sensitized solar cells (DSSCs) due to its strong visible light absorption and efficient electron transfer properties. It also serves as a catalyst in redox reactions, particularly in water oxidation processes for artificial photosynthesis. Additionally, its luminescent properties make it valuable in bioimaging and sensor development for detecting environmental pollutants.
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