Description

Ruthenium(2+), tris(4,7-diphenyl-1,10-phenanthroline-kappaN1,kappaN10)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2) is a high-purity coordination complex featuring a ruthenium(II) center ligated by three 4,7-diphenyl-1,10-phenanthroline ligands, with hexafluorophosphate counterions ensuring solubility and stability. This compound (CAS: 123148-15-2, Molecular Formula: C₇₂H₄₈F₁₂N₆P₂Ru) is a versatile photophysical material, prized for its strong luminescent properties and redox activity. Ideal for advanced electrochemical and optoelectronic research, it serves as a key component in dye-sensitized solar cells (DSSCs), light-emitting devices (OLEDs/LECs), and photocatalytic systems. Supplied as a crystalline solid with >95% purity, it is rigorously characterized by NMR, HPLC, and elemental analysis to meet stringent research standards. Store under inert conditions at -20°C to preserve performance.

Properties

• CAS Number: 123148-15-2
• Complexity: 472
• IUPAC Name: 4,7-diphenyl-1,10-phenanthroline;ruthenium(2+);dihexafluorophosphate
• InChI: InChI=1S/3C24H16N2.2F6P.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;2*1-7(2,3,4,5)6;/h3*1-16H;;;/q;;;2*-1;+2
• InChI Key: GUALHCKQGYAQFA-UHFFFAOYSA-N
• Exact Mass: 1388.226748
• Molecular Formula: C72H48F12N6P2Ru
• Molecular Weight: 1388.2
• SMILES: C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]
• Topological: 77.3
• Monoisotopic Mass: 1388.226748
• Synonyms: 123148-15-2, Ruthenium(2+), tris(4,7-diphenyl-1,10-phenanthroline-kappaN1,kappaN10)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2), 4,7-diphenyl-1,10-phenanthroline;ruthenium(2+);dihexafluorophosphate, SCHEMBL14810509, DTXSID30584984, AKOS025394270, FT99339, Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium bis(hexafluorophosphate), Ruthenium(2+) hexafluorophosphate–4,7-diphenyl-1,10-phenanthroline (1/2/3)

This ruthenium complex is widely used as a photosensitizer in dye-sensitized solar cells (DSSCs) due to its broad absorption spectrum and efficient charge transfer. It also functions as an emissive layer in electroluminescent devices (e.g., LECs) and as a catalyst in photoredox reactions. Researchers leverage its stable excited-state properties for mechanistic studies in artificial photosynthesis and molecular electronics.

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