Description

Platinum, dichloro((1,2,5,6-eta)-1,5-cyclooctadiene)- (CAS: 12080-32-9) is a highly specialized organometallic compound with the molecular formula C₈H₁₂Cl₂Pt. This platinum(II) complex features a 1,5-cyclooctadiene ligand coordinated in an η⁴ fashion, making it a versatile precursor in catalysis and materials science. With its high purity and stability, this compound is ideal for research in homogeneous catalysis, organic synthesis, and coordination chemistry. It is particularly valued for its role in C-C coupling reactions, hydrogenation processes, and as a starting material for other platinum complexes. Packaged under inert conditions to ensure longevity, this product meets the rigorous demands of academic and industrial researchers.

Properties

• CAS Number: 12080-32-9
• Complexity: 75.4
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;dichloroplatinum
• InChI: InChI=1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
• InChI Key: VVAOPCKKNIUEEU-PHFPKPIQSA-L
• Exact Mass: 372.996400
• Molecular Formula: C8H12Cl2Pt
• Molecular Weight: 374.17
• SMILES: C1/C=CCC/C=CC1.Cl[Pt]Cl
• Monoisotopic Mass: 372.996400
• Physical Description: Light yellow crystalline powder; Hygroscopic; Insoluble in water;
• Synonyms: Dichloro(1,5-cyclooctadiene)platinum(II), 1,5-Cyclooctadienedichloroplatinum, Dichloro(1,5-cyclooctadiene)platinum, NSC 239486, Platinum, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]-, EINECS 235-144-5, Platinum, dichloro(1,5-cyclooctadiene)-, Platinum, dichloro((1,2,5,6-eta)-1,5-cyclooctadiene)-, Dichloro((1,2,5,6-eta)-1,5-cyclooctadiene)platinum, Dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]platinum, 1,5Cyclooctadienedichloroplatinum, Dichloro(1,5cyclooctadiene)platinum, Platinum, dichloro(1,5cyclooctadiene), Dichloro((1,2,5,6eta)cycloocta1,5diene)platinum, Platinum, dichloro((1,2,5,6eta)1,5cyclooctadiene), 12080-32-9, dichloro(1,5-cyclooctadiene)platinum (II), Dichloro(cycloocta-1,5-diene)platinum(II), MFCD00012413, AKOS015964365, AC-5534, BP-12163, CS-0084597, (1Z,5Z)-cycloocta-1,5-diene;dichloroplatinum, Dichloro(1,5-cyclooctadiene)platinum ( cento), 10.14272/VVAOPCKKNIUEEU-PHFPKPIQSA-L.1, doi:10.14272/VVAOPCKKNIUEEU-PHFPKPIQSA-L.1, Q5272475

This platinum(II) complex is widely used as a catalyst in organic transformations, including cross-coupling reactions and hydrogenation processes. It serves as a precursor for synthesizing other platinum-based catalysts and materials. Researchers utilize it in studies of coordination chemistry due to its well-defined structure and reactivity. Its stability and solubility in common organic solvents make it suitable for lab-scale and industrial applications.

Safety and Hazards

GHS Hazard Statements

• H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
• H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
• H335 (96%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

Precautionary Statements

• P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501

Hazard Classes and Categories

• Skin Irrit. 2 (100%)
• Eye Irrit. 2 (100%)
• STOT SE 3 (96%)

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