Description
Lanthanum tris(trifluoromethanesulfonate) (CAS No. 52093-26-2) is a high-purity lanthanum-based triflate salt with the molecular formula C3F9LaO9S3. This compound is widely recognized for its strong Lewis acid properties, making it an excellent catalyst in organic synthesis, polymerization, and other specialized chemical reactions. Its trifluoromethanesulfonate (triflate) anions enhance solubility in polar organic solvents, ensuring efficient reactivity under mild conditions. Ideal for researchers and scientists, this product is rigorously tested for quality, ensuring consistent performance in demanding applications such as asymmetric synthesis, Friedel-Crafts reactions, and electrochemical studies. Available in various quantities, it is packaged under inert conditions to maintain stability and purity.
Properties
- CAS Number: 52093-26-2
- Complexity: 145
- IUPAC Name: lanthanum(3+);trifluoromethanesulfonate
- InChI: InChI=1S/3CHF3O3S.La/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
- InChI Key: WGJJZRVGLPOKQT-UHFFFAOYSA-K
- Exact Mass: 585.762436
- Molecular Formula: C3F9LaO9S3
- Molecular Weight: 586.1
- SMILES: C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[La+3]
- Topological: 197
- Monoisotopic Mass: 585.762436
- Synonyms: 52093-26-2, LANTHANUM TRIS(TRIFLUOROMETHANESULFONATE), DTXSID10370049, DTXCID00321085, 628-666-3, Lanthanum(III) trifluoromethanesulfonate, LANTHANUM TRIFLUOROMETHANESULFONATE, LANTHANUM TRIFLATE, LA(OTF)3, Lanthanum(III) triflate, lanthanum(3+);trifluoromethanesulfonate, Trifluoromethanesulfonic acid lanthanum salt, MFCD30724953, TRIS(TRIFLUOROMETHANESULFONATO)LANTHANUM, lanthanum(3+); trifluoromethanesulfonate, MFCD00077560, 34629-21-5, Lanthanum trifluoromethanesulfonate, anhydrous, SCHEMBL76748, WGJJZRVGLPOKQT-UHFFFAOYSA-K, AKOS015852936, GS-6836, T1293, lanthanum(3+) ion tritrifluoromethanesulfonate, F15430, A828920, Trifluoromethanesulfonic Acid Lanthanum(III) Salt, Lanthanum(III) trifluoromethanesulfonate, trace metals grade
Application
Lanthanum tris(trifluoromethanesulfonate) is a versatile Lewis acid catalyst used in organic synthesis, particularly in Friedel-Crafts alkylations and acylations. It is also employed in polymerization reactions due to its ability to activate monomers under mild conditions. Researchers utilize it in asymmetric synthesis and electrochemical applications where high reactivity and selectivity are required.
Safety and Hazards
GHS Hazard Statements
- H314 (12.8%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
- H315 (87.2%): Causes skin irritation [Warning Skin corrosion/irritation]
- H319 (87.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
- H335 (87.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
Precautionary Statements
- P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501
Hazard Classes and Categories
- Skin Corr. 1B (12.8%)
- Skin Irrit. 2 (87.2%)
- Eye Irrit. 2 (87.2%)
- STOT SE 3 (87.2%)
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