Description

Haloxyfop (CAS 69806-34-4) is a highly selective aryloxyphenoxypropionate herbicide known for its efficacy in post-emergence grass weed control. With the molecular formula C₁₅H₁₁ClF₃NO₄, this compound is chemically designated as 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid. It is widely used in agricultural research and crop protection studies due to its ability to inhibit acetyl-CoA carboxylase (ACCase), a critical enzyme in fatty acid biosynthesis. This product is supplied as a high-purity analytical standard or research-grade material, ideal for laboratory use, method development, and environmental monitoring. Suitable for GC-MS, HPLC, and LC-MS applications, Haloxyfop is rigorously tested to ensure consistency and reliability for scientific applications.

Properties

• CAS Number: 69806-34-4
• Complexity: 429
• IUPAC Name: 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridyl]oxy]phenoxy]propanoic acid
• InChI: InChI=1S/C15H11ClF3NO4/c1-8(14(21)22)23-10-2-4-11(5-3-10)24-13-12(16)6-9(7-20-13)15(17,18)19/h2-8H,1H3,(H,21,22)
• InChI Key: GOCUAJYOYBLQRH-UHFFFAOYSA-N
• Exact Mass: 361.0328700
• Molecular Formula: C15H11ClF3NO4
• Molecular Weight: 361.70
• SMILES: CC(C(=O)O)OC1=CC=C(C=C1)OC2=C(C=C(C=N2)C(F)(F)F)Cl
• Topological: 68.7
• Monoisotopic Mass: 361.0328700
• Synonyms: HALOXYFOP, 69806-34-4, 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid, Haloxyfop Acid, 24TYO6H90H, DTXSID7042019, 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridyl]oxy]phenoxy]propanoic acid, HALOXYFOP [ISO], 2-(4-((3-Chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoic acid, CHEBI:365, DTXCID5022019, Propanoic acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-, Propanoic acid, 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]-, haloxyfop-acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridyl)oxy)phenoxy)propanoic acid, 2-(4-(3-chloro-5-(trifluoromethyl)pyridin-2-yl)oxyphenoxy)propanoic acid, 2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propanoic acid, (RS)-2-(4-(3-chloro-5-(trifluoromethyl)-2-pyridyloxy)phenoxy)propionic acid, (RS)-2-(4-(3-Chloro-5-(trifluoromethyl-2-pyridyloxy)phenoxy)-propionic acid, (RS)-2-[4-(3-Chloro-5-(trifluoromethyl-2-pyridyloxy)phenoxy]-propionic acid, (rs)-2-{4-[3-chloro-5-(trifluoromethyl)-2-pyridyloxy]phenoxy}propionic acid, rac-(2R)-2-(4-((3-chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoic acid, rac-(2R)-2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid, rac-2-(4-((3-chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoic acid, rac-2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid, (+-)-HALOXYFOP, Propanoic acid, 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-(9CI), 615-015-3, 2-(4-((3-Chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoic acid, (+/-)-Haloxyfop, Haloxyfop [ANSI:BSI:ISO], Haloxyfop (free acid), MFCD00871401, (RS)-2-(4-(3-Chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy)propionic acid, Haloxyfop (free acid) 10 microg/mL in Acetonitrile, C15H11ClF3NO4, UNII-24TYO6H90H, (RS)-2-[4-(3-Chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid, 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid, Haloxyfop-d4, Haloxyfop (Standard), DE-535 acid, SCHEMBL33627, CHEMBL223593, HY-B1856R, (2S)-2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid, (S)-2-(4-((3-Chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoic acid, CHEBI:136694, CFA89334, HY-B1856, Tox21_301857, AKOS015963417, AG-G-72348, SB48726, NCGC00249119-01, NCGC00255831-01, AC-19977, AS-50000, SY107474, CAS-69806-34-4, DB-055348, CS-0013923, NS00066824, Haloxyfop, PESTANAL(R), analytical standard, C04871, O10467, Haloxyfop (free acid) 100 microg/mL in Acetonitrile, Q27105292, 2-(4-((3-Chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoicacid, 2-(4-(3-Chloro-5-trifluoromethyl-2-pyridyl-oxy)phenoxy) propionic acid, 2-(4-(3-Chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy) propionic acid, 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propionic acid, 2-[4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)-phenoxy]propionic acid

Application

Haloxyfop is primarily employed as a post-emergence herbicide for selective control of annual and perennial grasses in broadleaf crops such as soybeans, cotton, and peanuts. Its mechanism of action involves inhibition of ACCase, leading to disruption of lipid synthesis and eventual plant death. Researchers utilize Haloxyfop in studies on herbicide resistance, metabolic pathways, and environmental degradation. It is also applied in formulation development and efficacy testing for agricultural pest management.

Safety and Hazards

GHS Hazard Statements

• H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]
• H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
• H412 (100%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

Precautionary Statements

• P264, P264+P265, P270, P273, P280, P301+P317, P305+P354+P338, P317, P330, and P501

Hazard Classes and Categories

• Acute Tox. 4 (100%)
• Eye Dam. 1 (100%)
• Aquatic Chronic 3 (100%)

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Disclaimer: Sold exclusively for laboratory research. Prohibited for commercial use, diagnostics, or human/animal applications. Buyers assume all compliance liability.