Description
Di(4-t-butylphenyl)iodonium camphorsulfonate (CAS No. 193345-23-2) is a high-purity iodonium salt extensively utilized in advanced photochemical and catalytic applications. With the molecular formula C30H41IO4S, this compound features a unique cationic iodonium center paired with a camphorsulfonate anion, offering exceptional solubility and reactivity in organic matrices. Its IUPAC name, bis(2-tert-butylphenyl)iodanium;(7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonate, reflects its structurally optimized design for photoacid generation (PAG) in lithography, polymer curing, and specialty synthesis. Ideal for researchers requiring precise control over cationic polymerization or UV-triggered reactions, this product is rigorously tested for consistency, with ≥98% purity (HPLC) and low metal content (<5 ppm). Supplied in amber vials under inert packaging to ensure stability.
Properties
- CAS Number: 193345-23-2
- Complexity: 678
- IUPAC Name: bis(2-tert-butylphenyl)iodonium;(7,7-dimethyl-2-oxo-norbornan-1-yl)methanesulfonate
- InChI: InChI=1S/C20H26I.C10H16O4S/c1-19(2,3)15-11-7-9-13-17(15)21-18-14-10-8-12-16(18)20(4,5)6;1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7-14H,1-6H3;7H,3-6H2,1-2H3,(H,12,13,14)/q+1;/p-1
- InChI Key: GLZIUPBSZFTZJT-UHFFFAOYSA-M
- Exact Mass: 624.17703
- Molecular Formula: C30H41IO4S
- Molecular Weight: 624.6
- SMILES: CC1(C2CCC1(C(=O)C2)CS(=O)(=O)[O-])C.CC(C)(C)C1=CC=CC=C1[I+]C2=CC=CC=C2C(C)(C)C
- Topological: 82.7
- Monoisotopic Mass: 624.17703
- Synonyms: 193345-23-2, Di(4-t-butylphenyl)iodonium camphorsulfonate, 682-849-2, SCHEMBL59887, DB-429568, Bis(tert-butylphenyl)iodonium 10-camphorsulfonate
Application
Di(4-t-butylphenyl)iodonium camphorsulfonate serves as a highly efficient photoacid generator (PAG) in UV-curable coatings and photoresists, enabling rapid polymerization under light exposure. Its thermal stability and low volatility make it suitable for high-temperature lithographic processes in semiconductor manufacturing. Researchers also employ it in cationic epoxy curing and click chemistry due to its strong Brønsted acid release upon irradiation.
Safety and Hazards
GHS Hazard Statements
- H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
Precautionary Statements
- P264+P265, P280, P305+P354+P338, and P317
Hazard Classes and Categories
- Eye Dam. 1 (100%)
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