Description

Bis(2,2′-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) (CAS No. 84537-86-0) is a high-purity, organometallic ruthenium complex with the molecular formula C₃₂H₂₅F₁₂N₇P₂Ru. This compound features a ruthenium(II) center coordinated to two 2,2′-bipyridine ligands and one 5-aminophenanthroline ligand, with hexafluorophosphate counterions ensuring solubility in polar organic solvents. Its unique photophysical and electrochemical properties make it invaluable in advanced research applications. The product is rigorously characterized by NMR, HPLC, and elemental analysis to guarantee ≥95% purity, meeting the stringent demands of academic and industrial researchers. Supplied as a crystalline solid, it is stored under inert conditions to preserve stability.

Properties

• CAS Number: 84537-86-0
• Complexity: 413
• IUPAC Name: 1,10-phenanthrolin-5-amine;2-(2-pyridyl)pyridine;ruthenium(2+);dihexafluorophosphate
• InChI: InChI=1S/C12H9N3.2C10H8N2.2F6P.Ru/c13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12;2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h1-7H,13H2;2*1-8H;;;/q;;;2*-1;+2
• InChI Key: QQMMCXKCYXQNNA-UHFFFAOYSA-N
• Exact Mass: 899.049846
• Molecular Formula: C32H25F12N7P2Ru
• Molecular Weight: 898.6
• SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC2=CC(=C3C=CC=NC3=C2N=C1)N.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]
• Topological: 103
• Monoisotopic Mass: 899.049846
• Synonyms: 84537-86-0, Ru(bpy)2(phen-5-NH2)(PF6)2, Bis(2,2′-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate), 146441-73-8, BIS(BIPYRIDINE)-(5-AMINOPHENANTHROLINE)R, 1,10-phenanthrolin-5-amine;2-pyridin-2-ylpyridine;ruthenium(2+);dihexafluorophosphate, DTXSID30477241, MFCD20921517, H41344, Bis(2,2/’-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate), Bis(2,2′-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate), BioReagent, suitable for fluorescence

Application

This ruthenium complex is widely used as a photosensitizer in dye-sensitized solar cells (DSSCs) due to its strong visible light absorption and efficient charge transfer properties. It also serves as a catalyst in photoredox reactions, enabling C-C bond formation and other organic transformations under mild conditions. Researchers utilize it in electrochemiluminescence (ECL) assays for biomedical diagnostics, leveraging its stable luminescent signal. Additionally, it finds applications in molecular electronics and as a probe for studying electron transfer mechanisms in supramolecular systems.

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