Description

2,2,3,4,4,4-Hexafluorobutyl methacrylate (CAS No. 36405-47-7) is a high-purity fluorinated methacrylate monomer with the molecular formula C₈H₈F₆O₂. This specialty chemical is characterized by its hexafluorobutyl group, which imparts unique properties such as enhanced hydrophobicity, chemical resistance, and low surface energy. Ideal for advanced polymer synthesis, this monomer is widely used in the development of fluorinated acrylic resins, coatings, and adhesives. Its IUPAC name is 2,2,3,4,4,4-hexafluorobutyl 2-methylprop-2-enoate. Suitable for research and industrial applications, this compound is supplied with detailed technical documentation, including NMR and HPLC purity reports.

Properties

• CAS Number: 36405-47-7
• Complexity: 283
• IUPAC Name: 2,2,3,4,4,4-hexafluorobutyl 2-methylprop-2-enoate
• InChI: InChI=1S/C8H8F6O2/c1-4(2)5(15)16-3-7(10,11)6(9)8(12,13)14/h6H,1,3H2,2H3
• InChI Key: DFVPUWGVOPDJTC-UHFFFAOYSA-N
• Exact Mass: 250.04284847
• Molecular Formula: C8H8F6O2
• Molecular Weight: 250.14
• SMILES: CC(=C)C(=O)OCC(C(C(F)(F)F)F)(F)F
• Topological: 26.3
• Monoisotopic Mass: 250.04284847
• Synonyms: 2,2,3,4,4,4-Hexafluorobutyl methacrylate, 628-322-2, 36405-47-7, 1h,1h,3h-hexafluorobutyl methacrylate, 2,2,3,4,4,4-hexafluorobutyl 2-methylprop-2-enoate, 1H,1H,3H-Perfluorobutyl 2-methylacrylate, MFCD00042311, 2-Propenoic Acid 2-Methyl-2,2,3,4,4,4-Hexafluorobutyl Ester, 2,2,3,4,4,4-Hexafluorobutyl Methacrylate (stabilized with MEHQ), HFBMA, 2-Propenoic acid, 2-methyl-, 2,2,3,4,4,4-hexafluorobutyl ester, 2,2,3,4,4,4-Hexafluorobut-1-yl methacrylate, SCHEMBL36259, Methacrylic acid 2,2,3,4,4,4-hexafluorobutyl ester, DTXSID80880403, SBB070875, AKOS005254981, CS-W014626, FS-3851, H1555, NS00019006, F20385, 2,2,3,4,4,4-Hexafluorobutyl 2-methylacrylate #, 2,2,3,4,4,4-Hexafluorobutyl methacrylate, 98%, 2,2,3,4,4,4-HexafluorobutylMethacrylate(stabilizedwithMEHQ), 2-Methylpropenoic acid, 2,2,3,4,4,4-hexafluorobutyl ester, 2-METHYLACRYLIC ACID 2,2,3,4,4,4-HEXAFLUORO-BUTYL ESTER

Application

2,2,3,4,4,4-Hexafluorobutyl methacrylate is primarily used in the synthesis of fluorinated polymers and copolymers, which exhibit exceptional resistance to solvents, UV radiation, and weathering. It is a key component in high-performance coatings for aerospace, automotive, and electronic applications due to its low surface energy and anti-fouling properties. Researchers also utilize this monomer to develop advanced materials for biomedical devices and hydrophobic surfaces.

Safety and Hazards

GHS Hazard Statements

• H226 (97.9%): Flammable liquid and vapor [Warning Flammable liquids]
• H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
• H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
• H335 (97.9%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

Precautionary Statements

• P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501

Hazard Classes and Categories

• Flam. Liq. 3 (97.9%)
• Skin Irrit. 2 (100%)
• Eye Irrit. 2 (100%)
• STOT SE 3 (97.9%)

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Disclaimer: Sold exclusively for laboratory research. Prohibited for commercial use, diagnostics, or human/animal applications. Buyers assume all compliance liability.