Description

1,1,1,3,3,3-Hexafluoro-2-propyl methacrylate (HFIP-M) is a high-purity fluorinated methacrylate monomer designed for advanced applications in polymer science and specialty materials. This compound features a hexafluoroisopropyl group bonded to a methacrylate backbone, offering exceptional chemical resistance, low surface energy, and enhanced thermal stability. Its unique fluorinated structure makes it ideal for synthesizing hydrophobic, oleophobic, and highly durable polymers.

Supplied as a clear liquid stabilized with MEHQ to prevent premature polymerization, this monomer is rigorously tested to ensure consistency and performance in demanding research and industrial applications. Suitable for free-radical polymerization, it is commonly used in coatings, optical materials, and advanced composites where fluorinated properties are critical.

Handle with care in a well-ventilated environment, using appropriate personal protective equipment (PPE) due to its reactive nature. Store under inert conditions away from light and heat sources to maintain stability.

Properties

• CAS Number: 3063-94-3
• Complexity: 250
• IUPAC Name: [2,2,2-trifluoro-1-(trifluoromethyl)ethyl] 2-methylprop-2-enoate
• InChI: InChI=1S/C7H6F6O2/c1-3(2)4(14)15-5(6(8,9)10)7(11,12)13/h5H,1H2,2H3
• InChI Key: FMQPBWHSNCRVQJ-UHFFFAOYSA-N
• Exact Mass: 236.02719840
• Molecular Formula: C7H6F6O2
• Molecular Weight: 236.11
• SMILES: CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F
• Topological: 26.3
• Monoisotopic Mass: 236.02719840
• Synonyms: Hexafluoroisopropyl methacrylate, 2-Propenoic acid, 2-methyl-, 2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester, HFIP-M, 2,2,2-Trifluoro-1-(trifluoromethyl)ethyl methacrylate, DPH4JT6JRF, VISCOAT 6FM, EINECS 221-309-9, 1,1,1,3,3,3-HEXAFLUORO-2-PROPYL METHACRYLATE, DTXSID50883729, diperfluoromethylmethyl methacrylate, METHACRYLIC ACID, 2,2,2-TRIFLUORO-1-(TRIFLUOROMETHYL)ETHYL ESTER, DTXCID601023225, 221-309-9, 3063-94-3, 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate, 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate, 1,1,1,3,3,3-HEXAFLUOROISOPROPYLMETHACRYLATE, 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate (stabilized with MEHQ), HFIPMA, MFCD00040105, UNII-DPH4JT6JRF, SCHEMBL47311, FMQPBWHSNCRVQJ-UHFFFAOYSA-, 1,1,1,3,3,3-HEXAFLUOROPROPAN-2-YL METHACRYLATE, Methacrylic Acid 1,1,1,3,3,3-Hexafluoroisopropyl Ester, XODRGRKHTIMSHE-UHFFFAOYSA-N, SBB098524, AKOS005257996, HFIPMA; Hexafluoroisopropyl methacrylate, FH167866, MS-20605, DB-047824, CS-0127663, M0988, NS00047896, A10439, 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate, 99%, 2,2,2-Trifluoro-1-(trifluoromethyl)ethyl 2-methylacrylate #, 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate(stabilizedwithMEHQ), 2,2,2-trifluoro-1-(trifluoromethyl)ethyl 2-methylprop-2-enoate, 1,1,1,3,3,3-Hexafluoroisopropyl Methacrylate, (stabilized with MEHQ), 1 pound not1 pound not1 pound not3 pound not3 pound not3-Hexafluoroisopropyl methacrylate, 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate – Stabilized with 100-200 ppm MEHQ, InChI=1/C7H6F6O2/c1-3(2)4(14)15-5(6(8,9)10)7(11,12)13/h5H,1H2,2H3

1,1,1,3,3,3-Hexafluoro-2-propyl methacrylate is widely employed in the development of fluoropolymer coatings with superior water and oil repellency, making it valuable for aerospace and automotive surfaces. Its low refractive index and high transparency also render it useful in optical applications, such as lenses and waveguides. Researchers utilize this monomer to create specialty adhesives and sealants with enhanced chemical resistance for extreme environments.

Safety and Hazards

GHS Hazard Statements

• H225 (92.3%): Highly Flammable liquid and vapor [Danger Flammable liquids]
• H302 (80.8%): Harmful if swallowed [Warning Acute toxicity, oral]
• H312 (80.8%): Harmful in contact with skin [Warning Acute toxicity, dermal]
• H315 (94.2%): Causes skin irritation [Warning Skin corrosion/irritation]
• H319 (94.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
• H332 (80.8%): Harmful if inhaled [Warning Acute toxicity, inhalation]
• H335 (90.4%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

Precautionary Statements

• P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501

Hazard Classes and Categories

• Flam. Liq. 2 (92.3%)
• Acute Tox. 4 (80.8%)
• Acute Tox. 4 (80.8%)
• Skin Irrit. 2 (94.2%)
• Eye Irrit. 2 (94.2%)
• Acute Tox. 4 (80.8%)
• STOT SE 3 (90.4%)

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Disclaimer: Sold exclusively for laboratory research. Prohibited for commercial use, diagnostics, or human/animal applications. Buyers assume all compliance liability.