Description

3,6,9-Triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexoxonane (CAS No. 24748-23-0) is a high-purity organic peroxide with the molecular formula C₁₂H₂₄O₆. This specialized compound, also known by its IUPAC name 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxonane, is widely utilized as a radical initiator in polymerization reactions. Its unique cyclic structure and peroxide groups make it highly effective for controlled radical generation under thermal decomposition. Available in liquid or solid form, this product is rigorously tested for stability, purity, and reactivity to ensure consistent performance in demanding chemical processes. Proper storage at recommended temperatures is essential to maintain its efficacy and safety profile.

Properties

• CAS Number: 24748-23-0
• Complexity: 212
• IUPAC Name: 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxonane
• InChI: InChI=1S/C12H24O6/c1-7-10(4)13-15-11(5,8-2)17-18-12(6,9-3)16-14-10/h7-9H2,1-6H3
• InChI Key: KVWLLOIEGKLBPA-UHFFFAOYSA-N
• Exact Mass: 264.15728848
• Molecular Formula: C12H24O6
• Molecular Weight: 264.31
• SMILES: CCC1(OOC(OOC(OO1)(C)CC)(C)CC)C
• Topological: 55.4
• Monoisotopic Mass: 264.15728848
• Physical Description: Liquid
• Synonyms: 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexoxonane, 24748-23-0, Trigonox 301, UNII-J3MV6AZN38, J3MV6AZN38, 1,2,4,5,7,8-Hexoxonane, 3,6,9-triethyl-3,6,9-trimethyl-, DTXSID3051913, DTXCID8030475, 429-320-2, 607-429-8, 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxonane, SCHEMBL891987, NS00008295, Q27281161, 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxacyclononane, 1,2,4,5,7,8-hexaoxacyclononane, 3,6,9-trimethyl, 3,6,9-triethyl

Application

This compound serves as a highly efficient initiator for polymerization reactions, particularly in the production of polyethylene and other thermoplastic materials. Its controlled decomposition properties make it ideal for industrial applications requiring precise radical generation at specific temperature ranges. Researchers also utilize it in organic synthesis for creating cross-linked polymers with tailored molecular weights and structures.

Safety and Hazards

GHS Hazard Statements

• H241 (100%): Heating may cause a fire or explosion [Danger Self-reactive substances and mixtures; Organic peroxides]
• H304 (100%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]
• H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
• H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]

Precautionary Statements

• P210, P234, P235, P240, P261, P264, P272, P280, P301+P316, P302+P352, P321, P331, P332+P317, P333+P317, P362+P364, P370+P380+P375[+P378], P403, P405, P410, P411, P420, and P501

Hazard Classes and Categories

• Org. Perox. B (100%)
• Asp. Tox. 1 (100%)
• Skin Irrit. 2 (100%)
• Skin Sens. 1 (100%)

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