Description

Perfluorohexylethyl acrylate (CAS No. 17527-29-6) is a high-purity fluorinated acrylate ester with the molecular formula C₁₁H₇F₁₃O₂. This compound, also known as 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl prop-2-enoate, is characterized by its exceptional hydrophobic and oleophobic properties due to the presence of a perfluorinated hexyl chain. It is widely utilized in advanced material science, particularly in the synthesis of fluoropolymers and surface-modifying agents. The product is supplied as a clear, colorless to pale yellow liquid with a high degree of chemical stability and low surface energy, making it ideal for applications requiring water and oil repellency. Suitable for research and industrial use, it is packaged under inert conditions to ensure maximum shelf life and performance consistency.

Properties

• CAS Number: 17527-29-6
• Complexity: 535
• IUPAC Name: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl prop-2-enoate
• InChI: InChI=1S/C11H7F13O2/c1-2-5(25)26-4-3-6(12,13)7(14,15)8(16,17)9(18,19)10(20,21)11(22,23)24/h2H,1,3-4H2
• InChI Key: VPKQPPJQTZJZDB-UHFFFAOYSA-N
• Exact Mass: 418.0238456
• Molecular Formula: C11H7F13O2
• Molecular Weight: 418.15
• SMILES: C=CC(=O)OCCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Topological: 26.3
• Monoisotopic Mass: 418.0238456
• Physical Description: Liquid
• Synonyms: 17527-29-6, 1h,1h,2h,2h-perfluorooctyl acrylate, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl acrylate, 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl ester, perfluorohexylethyl acrylate, 2-(Perfluorohexyl)ethyl acrylate, 1,1,2,2-Tetrahydroperfluorooctyl acrylate, H8RP8R77R9, CHEMINOX FAAC 6, EINECS 241-527-8, ACTYFLON G 06C, EC 241-527-8, ACRYLIC ACID, 3,3,4,4,5,5,6,6,7,7,8,8,8-TRIDECAFLUOROOCTYL ESTER, 241-527-8, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl prop-2-enoate, 1H,1H,2H,2H-Tridecafluoro-n-octyl Acrylate, MFCD00042351, (perfluorohexyl)ethyl acrylate, C11H7F13O2, 1H,1H,2H,2H-Tridecafluoro-n-octyl Acrylate (stabilized with HQ + MEHQ), Acrylic Acid 1H,1H,2H,2H-Tridecafluoro-n-octyl Ester, UNII-H8RP8R77R9, 6:2 Fluorotelomer acrylate, SCHEMBL347405, DTXSID9038840, MSK14749, BBL102116, FD2032, STL555915, 95% (stabilized with MEHQ or TBC), AKOS005762865, MSK14749-1000A, SB66411, 1H,1H,2H,2H-Tridecafluorooctyl acrylate, AS-48916, DA-24820, SY050308, CS-0121608, NS00008296, T3021, T3451, Q27279771, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylacrylate, 1H,1H,2H,2H-Tridecafluoro-n-octyl Acrylate (stabilized with MEHQ), 1H,1H,2H,2H-Perfluorooctyl acrylate Solution in Acetonitrile, 1000ug/mL, Acrylic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylester, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl acrylate, contains inhibitor, 97%, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl acrylate, 97%, contains 100 ppm TBC as stabilizer

Application

Perfluorohexylethyl acrylate is primarily used in the development of hydrophobic and oleophobic coatings for textiles, electronics, and medical devices. Its fluorinated side chain enhances surface properties, making it valuable in creating self-cleaning and anti-fouling materials. Additionally, it serves as a key monomer in the synthesis of specialty fluoropolymers with applications in high-performance lubricants and adhesives. Researchers also employ it in nanotechnology for modifying surface interactions at the micro- and nano-scale.

Safety and Hazards

GHS Hazard Statements

• H315 (17.1%): Causes skin irritation [Warning Skin corrosion/irritation]
• H319 (17.1%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
• H335 (23.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
• H373 (67.8%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]

Precautionary Statements

• P260, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501

Hazard Classes and Categories

• Skin Irrit. 2 (17.1%)
• Eye Irrit. 2 (17.1%)
• STOT SE 3 (23.3%)
• STOT RE 2 (67.8%)

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