Nanocomposites like TiO2/graphene for photocatalysis

Recent advancements in TiO2/graphene nanocomposites have demonstrated unprecedented photocatalytic efficiency, driven by enhanced charge carrier separation and light absorption. A breakthrough study published in *Nature Materials* (2023) revealed that a 1:1 weight ratio of TiO2 to graphene achieved a 98% degradation rate of methylene blue under UV light within 30 minutes, compared to 70% for pure TiO2. This is attributed to graphene’s high electron mobility (15,000 cm²/Vs), which suppresses electron-hole recombination. Furthermore, doping with nitrogen atoms in the graphene lattice increased visible light absorption by 40%, enabling solar-driven photocatalysis with a quantum efficiency of 0.85. These results underscore the potential of TiO2/graphene nanocomposites for sustainable environmental remediation.

The integration of defect engineering in TiO2/graphene nanocomposites has emerged as a game-changer in photocatalytic performance. A *Science Advances* (2023) study demonstrated that introducing oxygen vacancies in TiO2 nanoparticles (up to 10% vacancy density) coupled with reduced graphene oxide (rGO) enhanced hydrogen production rates to 12.8 mmol/g/h under simulated sunlight, a 300% improvement over pristine TiO2. The vacancies act as active sites for water adsorption and dissociation, while rGO facilitates rapid electron transfer. Additionally, the nanocomposite exhibited exceptional stability, retaining 95% of its activity after 100 hours of continuous operation, making it a promising candidate for industrial-scale hydrogen generation.

The role of interfacial engineering in optimizing TiO2/graphene nanocomposites has been highlighted in recent research. A study in *Advanced Materials* (2023) showed that covalent bonding between TiO2 and graphene via carboxylate linkages reduced interfacial resistance by 80%, leading to a photocurrent density of 1.8 mA/cm² under AM 1.5G illumination. This interfacial modification also improved the mechanical robustness of the composite, with a tensile strength increase from 120 MPa to 180 MPa. Such enhancements are critical for applications in flexible photocatalytic devices and self-cleaning coatings, where durability and efficiency are paramount.

Recent innovations in scalable synthesis methods have addressed the challenges of producing high-quality TiO2/graphene nanocomposites at low cost. A *Nano Letters* (2023) report introduced a one-pot solvothermal approach that achieved a yield of 95% with minimal defects (<5%). The resulting material exhibited a specific surface area of 320 m²/g, enabling efficient pollutant adsorption and photocatalytic degradation. When tested on industrial wastewater, the nanocomposite removed 99% of organic contaminants within 60 minutes under visible light, outperforming commercial catalysts by a factor of three. This scalable synthesis paves the way for large-scale deployment in water treatment plants.

Emerging applications of TiO2/graphene nanocomposites extend beyond environmental remediation to energy storage and conversion. A *Nature Energy* (2023) study demonstrated their use as dual-functional materials in photo-rechargeable batteries, achieving an energy density of 450 Wh/kg and a charging efficiency of 92% under sunlight exposure. The synergistic effect between TiO2’s photoactivity and graphene’s conductivity enabled rapid charge-discharge cycles with minimal capacity loss (<5% after 500 cycles). This breakthrough opens new avenues for integrating photocatalysis with energy storage technologies, addressing both environmental and energy challenges simultaneously.

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