MXene-based tribological coatings for wear resistance

MXenes, a class of two-dimensional transition metal carbides, nitrides, and carbonitrides, have emerged as a revolutionary material for tribological coatings due to their exceptional mechanical properties and self-lubricating capabilities. Recent studies have demonstrated that Ti3C2Tx MXene coatings exhibit a coefficient of friction (COF) as low as 0.08 under dry sliding conditions, outperforming traditional materials like graphite and MoS2. The inherent layered structure of MXenes allows for easy shearing between layers, reducing friction and wear. Additionally, the high hardness (up to 12 GPa) and Young’s modulus (∼330 GPa) of MXenes contribute to their wear resistance, making them ideal for applications in extreme environments such as aerospace and automotive industries. Experimental results show that MXene coatings can reduce wear rates by up to 90% compared to uncoated substrates.

The tribological performance of MXene-based coatings can be further enhanced through functionalization and composite formation. For instance, the incorporation of graphene oxide (GO) into Ti3C2Tx MXene matrices has been shown to reduce the COF to 0.05 while increasing the wear life by over 200%. The synergistic effect between MXenes and GO arises from the formation of a robust tribofilm that minimizes direct contact between sliding surfaces. Moreover, doping MXenes with elements such as nitrogen or sulfur has been found to improve their thermal stability and oxidation resistance, enabling their use in high-temperature applications (up to 500°C). Recent experiments reveal that nitrogen-doped MXene coatings maintain a COF below 0.1 even after 10,000 cycles at elevated temperatures.

The scalability and adaptability of MXene-based coatings for industrial applications have been validated through advanced deposition techniques such as electrophoretic deposition (EPD) and chemical vapor deposition (CVD). EPD has been particularly effective in producing uniform MXene coatings with thicknesses ranging from 100 nm to 5 µm, achieving wear rates as low as 1.2 × 10^-6 mm³/Nm. CVD, on the other hand, enables the synthesis of hybrid MXene-metal composites with enhanced adhesion strength (>50 MPa) and durability. These techniques have facilitated the integration of MXene coatings onto complex geometries and diverse substrates, including steel, aluminum, and polymers.

Environmental sustainability is another critical advantage of MXene-based tribological coatings. Unlike conventional lubricants that often contain harmful additives, MXenes are inherently eco-friendly due to their composition of non-toxic elements such as titanium and carbon. Furthermore, their long-lasting performance reduces the need for frequent reapplication or replacement, minimizing waste generation. Life cycle assessments indicate that MXene coatings can reduce the environmental impact of tribological systems by up to 40% compared to traditional solutions.

Future research directions for MXene-based tribological coatings include exploring novel architectures such as vertically aligned nanosheets and hierarchical structures to further optimize their performance. Computational modeling has predicted that vertically aligned Ti3C2Tx nanosheets could achieve COFs below 0.03 under specific loading conditions. Additionally, integrating smart functionalities such as self-healing or stimuli-responsive behavior could open new avenues for adaptive tribological systems capable of dynamically adjusting their properties in response to external stimuli.

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