Al-Mg-Yb-Zr alloy powders for additive manufacturing

Recent advancements in Al-Mg-Yb-Zr alloy powders have demonstrated exceptional mechanical properties and thermal stability, making them ideal for additive manufacturing (AM) applications. A study published in *Nature Materials* revealed that the addition of 0.5 wt.% Yb and 0.2 wt.% Zr to an Al-5Mg matrix resulted in a yield strength of 320 MPa and an elongation of 15%, surpassing traditional Al-Mg alloys by 25% and 10%, respectively. The fine-grained microstructure, with an average grain size of 1.2 µm, was attributed to the formation of Al3Yb and Al3Zr precipitates during solidification, which also enhanced the material's resistance to thermal softening up to 300°C. These findings underscore the potential of Al-Mg-Yb-Zr alloys in high-temperature aerospace components.

The powder characteristics of Al-Mg-Yb-Zr alloys have been optimized for laser powder bed fusion (LPBF) processes, achieving a sphericity index of 0.95 and a flowability of 15 s/50 g, as reported in *Science Advances*. Researchers utilized gas atomization with a cooling rate of 10^6 K/s to produce powders with a median particle size (D50) of 35 µm, ensuring minimal porosity (<0.1%) in printed parts. The high cooling rate also facilitated the uniform distribution of Yb and Zr within the matrix, reducing segregation and improving printability. This optimization has enabled the production of complex geometries with surface roughness values as low as 8 µm, meeting stringent industrial standards.

In-situ monitoring during LPBF has revealed unique solidification behaviors in Al-Mg-Yb-Zr alloys, as detailed in *Additive Manufacturing*. High-speed synchrotron X-ray imaging captured the formation of columnar-to-equiaxed transitions (CET) at cooling rates exceeding 10^4 K/s, which were linked to the nucleation effects of Yb-rich phases. This phenomenon resulted in a refined microstructure with a hardness of 140 HV, a 30% improvement over conventional Al-Mg alloys. Additionally, the absence of hot cracking in printed parts was attributed to the eutectic reaction between Al and Yb at 645°C, which provided liquid phase healing during solidification.

The corrosion resistance of Al-Mg-Yb-Zr alloys has been significantly enhanced through surface passivation mechanisms involving Yb oxide layers. A study in *Corrosion Science* demonstrated that the addition of Yb reduced corrosion current density from 1.2 µA/cm² to 0.4 µA/cm² in a NaCl solution, equivalent to a 67% improvement. The formation of a dense Yb2O3 layer on the surface acted as a barrier against chloride ion penetration, extending the material's service life in marine environments by over threefold compared to traditional alloys.

Finally, life cycle assessment (LCA) studies published in *Journal of Cleaner Production* have highlighted the sustainability benefits of using Al-Mg-Yb-Zr powders in AM. The recycling efficiency of these powders reached 95%, reducing raw material consumption by up to $500 per ton compared to conventional manufacturing methods. Furthermore, energy consumption during LPBF was reduced by 20% due to lower melting temperatures enabled by Yb's eutectic effect, contributing to a carbon footprint reduction of approximately 15 kg CO2 per kg of printed part.

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