Organic solar cells (OSCs) leverage the unique properties of organic semiconductors, such as polymers and small molecules, to convert sunlight into electricity. These materials offer advantages such as flexibility, lightweight, and low-cost production, making them ideal for applications in wearable electronics and building-integrated photovoltaics (BIPV). OSCs typically consist of a bulk heterojunction (BHJ) structure, where donor and acceptor materials are blended to form an interpenetrating network. This structure enables efficient charge separation and transport, achieving power conversion efficiencies (PCEs) of over 18% in lab-scale devices. Research is focused on developing new donor and acceptor materials, optimizing the BHJ morphology, and improving device stability. For example, the use of non-fullerene acceptors, such as ITIC and Y6, has significantly enhanced the performance of OSCs, achieving PCEs of over 16% in large-area modules.
The fabrication of OSCs involves solution-based techniques, such as spin-coating, blade-coating, and inkjet printing, which enable low-cost and scalable production. Spin-coating is commonly used for lab-scale devices, achieving PCEs of over 18%, while blade-coating and inkjet printing are being developed for large-area modules. The integration of OSCs with tandem architectures, combining organic materials with perovskites or other semiconductors, is also being explored to achieve PCEs of over 20%. For example, organic-perovskite tandem cells have demonstrated PCEs of 21.6%, surpassing the efficiency limits of single-junction organic cells. These advancements are driving the commercialization of OSCs, with market projections estimating the global organic solar cell market to reach $1.2 billion by 2028, growing at a CAGR of 15.3%.
From a futuristic perspective, OSCs are expected to enable the development of lightweight, flexible, and semi-transparent solar cells for applications in wearable electronics, BIPV, and portable power systems. The exploration of hybrid organic systems, combining organic materials with other nanomaterials like quantum dots or 2D materials, is opening new avenues for innovation. Beyond photovoltaics, organic semiconductors are being considered for applications in LEDs, photodetectors, and sensors, where their unique properties can be leveraged to enhance performance. The convergence of materials science, chemistry, and engineering is accelerating the realization of OSC-based technologies, heralding a new era of flexible and low-cost optoelectronics.
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