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ZIF-8 MOF Powder (Solution-Processed, CAS 59061-53-9) ?C High-Porosity Zeolitic Imidazolate Framework
ZIF-8 (CAS 59061-53-9, KAR-F02) is a premium zeolitic imidazolate framework (ZIF) powder synthesized via a solution-based method, ensuring uniform particle size and exceptional crystallinity. This zinc-based MOF features a sodalite-like structure with ultrahigh surface area and chemical stability, making it ideal for gas adsorption (CO?, H?), molecular sieving, and heterogeneous catalysis. Its hydrophobic nature enhances performance in humid environments, while its tunable pore size enables selective separation of small molecules. Suitable for both academic research and industrial applications, ZIF-8 offers reliable performance in carbon capture, fuel storage, and chemical synthesis.
Description
Key Properties & Advantages
ZIF-8 (KAR-F02)??s superior performance stems from its sodalite-like structure and zinc-imidazolate chemistry:
Sodalite-Like Framework: Features a well-defined porous network with uniform pores (~3.4 ?) and a large BET surface area (typically 1400?C1900 m2/g), enabling efficient molecular sieving and high-capacity gas adsorption.
Exceptional Chemical Stability: Maintains structural integrity in organic solvents, aqueous solutions (pH 4?C12), and moderate temperatures (up to 250??C under inert conditions), outperforming many MOFs in harsh operational environments.
Hydrophobic Nature: Repels water molecules, preserving adsorption efficiency in humid environments??critical for applications like flue gas carbon capture, where moisture is present.
Tunable Pore Size & Surface Chemistry: Supports post-synthetic modification to adjust pore dimensions and functional groups, enhancing selectivity for target molecules (e.g., CO? over N?, H? over CH?).
Uniform Particle Size: Solution-based synthesis ensures consistent particle morphology, facilitating reliable packing in industrial columns and uniform dispersion in composite materials (e.g., membranes, catalytic supports).
Core Applications
Gas Adsorption & Storage
ZIF-8 (KAR-F02)??s porosity and stability make it ideal for gas-related applications:
CO? Capture: Selectively adsorbs CO? from flue gases, biogas, and ambient air, with high capacity and reversible adsorption??supporting carbon reduction efforts.
Hydrogen (H?) Storage: Efficiently captures and releases H? at low temperatures, enabling compact, safe storage for hydrogen fuel technologies.
Small Molecule Storage: Adsorbs other small gases (e.g., CH?, N?) with high selectivity, supporting fuel storage and industrial gas separation.
Molecular Sieving
Precision Separation: ~3.4 ? pores enable size-based separation of small molecules (e.g., CO? vs. N?, H? vs. CH?), critical for purifying industrial gas streams and fuel mixtures.
Solvent Purification: Removes impurities from organic solvents via selective adsorption, enhancing purity in pharmaceutical and fine chemical synthesis.
Heterogeneous Catalysis
Catalytic Support & Active Site: Zinc nodes act as Lewis acid sites, promoting reactions like esterification, cycloadditions, and CO? conversion. Its porous structure confines reactants, enhancing catalytic selectivity.
Stable Catalyst Platform: Withstands reaction conditions (e.g., high temperatures, organic solvents) without degradation, enabling repeated use in industrial catalytic cycles.
Technical Specifications
Parameter Details
CAS Number 59061-53-9
Chemical Composition Zinc 2-methylimidazolate (Zn(C?H?N?)?)
Appearance White to off-white crystalline powder
BET Surface Area 1400?C1900 m2/g
Pore Size ~3.4 ? (uniform micropores)
Thermal Stability Up to 250??C (inert atmosphere)
pH Stability 4?C12 (aqueous solutions)
Hydrophobicity Water-repellent, maintains activity in humid environments
Quality Assurance
Each batch of ZIF-8 (KAR-F02) undergoes rigorous testing:
X-ray Diffraction (XRD): Confirms crystallinity and sodalite-like structure.
Nitrogen Adsorption-Desorption: Verifies surface area and pore size distribution.
Scanning Electron Microscopy (SEM): Ensures uniform particle size and morphology.
Gas Adsorption Testing: Measures CO? and H? uptake to validate performance.
A certificate of analysis (CoA) is provided with each order, documenting batch-specific properties.
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