Atomfair Diphenyl-o-tolylphosphine C19H17P

Description Diphenyl-o-tolylphosphine (CAS No. 17511-60-3) is a high-purity organophosphorus compound with the molecular formula C19H17P and IUPAC name (2-methylphenyl)-diphenylphosphane . This air-sensitive phosphine ligand is widely utilized in coordination chemistry and catalysis due to its electron-donating properties and steric bulk. Our product is rigorously tested to ensure ??98% purity (GC) and is supplied as a crystalline solid under inert atmosphere packaging to maintain stability. Key applications include use as a precursor in transition metal complexes for cross-coupling reactions (Suzuki, Heck) and asymmetric hydrogenation catalysts. The ortho-tolyl group provides enhanced steric hindrance compared to simple triphenylphosphine, making it valuable for controlling…

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Description

Description

Diphenyl-o-tolylphosphine (CAS No. 17511-60-3) is a high-purity organophosphorus compound with the molecular formula C19H17P and IUPAC name (2-methylphenyl)-diphenylphosphane. This air-sensitive phosphine ligand is widely utilized in coordination chemistry and catalysis due to its electron-donating properties and steric bulk. Our product is rigorously tested to ensure ??98% purity (GC) and is supplied as a crystalline solid under inert atmosphere packaging to maintain stability.

Key applications include use as a precursor in transition metal complexes for cross-coupling reactions (Suzuki, Heck) and asymmetric hydrogenation catalysts. The ortho-tolyl group provides enhanced steric hindrance compared to simple triphenylphosphine, making it valuable for controlling selectivity in metal-mediated transformations. Proper handling under nitrogen/argon is recommended due to sensitivity to oxidation.

Available in research quantities (1g to 100g) with optional custom packaging. SDS and Certificate of Analysis provided with all orders.

  • CAS No: 17511-60-3
  • Molecular Formula: C19H17P
  • Molecular Weight: 276.3
  • Exact Mass: 276.106787540
  • Monoisotopic Mass: 276.106787540
  • IUPAC Name: (2-methylphenyl)-diphenylphosphane
  • SMILES: CC1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3
  • Synonyms: 5931-53-3, Diphenyl-o-tolylphosphine, EINECS 227-675-6, DTXSID40208048, DTXCID60130539

Application

Diphenyl-o-tolylphosphine serves as an effective ligand in palladium-catalyzed cross-coupling reactions, where its steric bulk improves catalyst stability and selectivity. The compound finds particular utility in asymmetric synthesis when complexed with rhodium or ruthenium for enantioselective hydrogenations. Researchers also employ it as a precursor for synthesizing photoactive metal complexes in materials science applications.

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