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Atomfair Carbonylchlorobis(triphenylphosphine)rhodium(I), trans- trans-RhCl(CO)(PPh3)2 C37H30ClOP2Rh-

Description Carbonylchlorobis(triphenylphosphine)rhodium(I), trans- (CAS No. 13938-94-8) is a highly specialized organometallic compound with the molecular formula C37H30ClOP2Rh . This air-stable, crystalline complex features a rhodium(I) center coordinated to a carbonyl ligand, a chloride, and two triphenylphosphine (PPh3) groups in a trans configuration. Widely recognized for its catalytic properties, this compound is a valuable precursor in homogeneous catalysis, particularly in hydrogenation, hydroformylation, and carbonylation reactions. Its high purity and well-defined structure make it ideal for research in organometallic chemistry, asymmetric synthesis, and industrial catalytic processes. Packaged under inert conditions to ensure stability, this product is suited for laboratory and pilot-scale applications.

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Description

Description

Carbonylchlorobis(triphenylphosphine)rhodium(I), trans- (CAS No. 13938-94-8) is a highly specialized organometallic compound with the molecular formula C37H30ClOP2Rh. This air-stable, crystalline complex features a rhodium(I) center coordinated to a carbonyl ligand, a chloride, and two triphenylphosphine (PPh3) groups in a trans configuration. Widely recognized for its catalytic properties, this compound is a valuable precursor in homogeneous catalysis, particularly in hydrogenation, hydroformylation, and carbonylation reactions. Its high purity and well-defined structure make it ideal for research in organometallic chemistry, asymmetric synthesis, and industrial catalytic processes. Packaged under inert conditions to ensure stability, this product is suited for laboratory and pilot-scale applications.

  • CAS No: 13938-94-8
  • Molecular Formula: C37H30ClOP2Rh-
  • Molecular Weight: 690.9
  • Exact Mass: 690.05154
  • Monoisotopic Mass: 690.05154
  • Charge: -1
  • IUPAC Name: carbon monoxide;rhodium;triphenylphosphane;chloride
  • SMILES: [C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
  • Synonyms: Carbonylchlorobis(triphenylphosphine)rhodium, 13938-94-8, trans-RhCl(CO)(PPh3)2, 100LRS254G, DTXSID501336350

Application

This rhodium(I) complex is extensively used as a catalyst in hydrogenation reactions, particularly for converting alkenes to alkanes under mild conditions. It also serves as a key precursor in hydroformylation processes, enabling the production of aldehydes from olefins. Additionally, researchers employ it in carbon-carbon bond-forming reactions, such as Heck and Suzuki couplings, due to its efficient oxidative addition properties.

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