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MIL-53(Al) Metal-Organic Framework Powder (CAS 654061-20-8) – Flexible Pore Structure for Smart Gas Control
MIL-53(Al) (CAS 654061-20-8, KAR-F46) is a premium aluminum metal-organic framework powder featuring a unique flexible framework structure. This intelligent material automatically adjusts its pore dimensions in response to environmental conditions, enabling superior performance in gas storage and separation applications. The framework’s breathing behavior allows for efficient capture and release of various gases including CO?, CH?, and H?, making it particularly valuable for carbon capture, natural gas storage, and hydrogen purification systems. With excellent thermal stability and reproducible quality, this MOF powder is suitable for both research purposes and industrial-scale applications in energy and environmental technologies.
Description
Key Properties & Advantages
MIL-53(Al) (KAR-F46)??s performance is defined by its flexible framework and aluminum-based chemistry:
Flexible Porous Structure: Exhibits a unique ??breathing?? behavior??pressure and temperature changes induce reversible pore expansion/contraction, dynamically tuning selectivity for gas adsorption. This adaptability is critical for targeted separation processes.
High Surface Area (??1000 m2/g): Maximizes active sites for gas interaction, enhancing adsorption capacity in CO? capture and gas separation applications.
Aluminum-Based Stability & Safety:
Chemical Stability: Maintains structural integrity in aqueous solutions (pH 3?C11) and organic solvents, ensuring durability in industrial environments.
Thermal Resilience: Withstands temperatures up to 300??C (inert atmosphere), supporting high-temperature adsorption-desorption cycles.
Low Toxicity: Aluminum??s inherent biocompatibility makes it suitable for applications requiring minimal environmental impact, unlike heavy metal-based MOFs.
Uniform Particle Size (1?C3 ??m): Ensures consistent packing in columns, efficient mass transport, and reliable performance in scalable systems (e.g., gas separation modules).
Core Applications
CO? Capture & Gas Separation
MIL-53(Al)??s flexible structure makes it a standout for carbon capture and gas separation:
CO? Selective Adsorption: Its ??breathing?? behavior enhances selectivity for CO? over N?, CH?, and other gases, enabling efficient capture from flue gases, biogas, and ambient air.
Dynamic Gas Separation: Pressure/temperature adjustments allow tailored separation of gas mixtures (e.g., CO?/CH?, C?H?/C?H?), adapting to varying industrial stream compositions without reconfiguring equipment.
Catalytic Sensors & Harmful Gas Detection
Toxic Gas Sensing: Demonstrates high sensitivity to harmful gases like isobutyraldehyde (a volatile organic compound, VOC), making it a promising material for catalytic sensors in industrial safety and air quality monitoring.
Sensor Stability: Aluminum??s low reactivity ensures long-term sensor performance, with minimal drift in detection accuracy over time.
Technical Specifications
Parameter Details
CAS Number 654061-20-8
Product Name MIL-53(Al)
Model KAR-F46
Metal Node Aluminum (Al3?)
Particle Size 1?C3 ??m
BET Surface Area ??1000 m2/g
Pore Size 0.4?C0.8 nm (flexible, ??breathing?? pores)
Thermal Stability Up to 300??C (inert atmosphere)
pH Stability 3?C11 (aqueous solutions)
Quality Assurance
Each batch of KAR-F46 undergoes rigorous testing to ensure consistency:
X-ray Diffraction (XRD): Confirms ??breathing?? behavior and structural integrity.
Nitrogen Adsorption-Desorption: Verifies surface area (??1000 m2/g) and pore size distribution.
Gas Adsorption Testing: Validates CO? selectivity and responsiveness to pressure/temperature changes.
Particle Size Analysis: Ensures uniformity (1?C3 ??m) via laser diffraction.
A certificate of analysis (CoA) is provided with each order, documenting batch-specific properties.
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