UIO-66-OH MOF Powder CAS: 1334721-91-3 | Hydroxylated Metal-Organic Framework | KAR-F30-OH

UIO-66-OH (CAS: 1334721-91-3) is an important derivative of the UIO-66 series, where hydroxyl modification endows the material with unique surface chemistry. This MOF retains the inherent high surface area and remarkable stability of UIO-66 series, while the introduced hydroxyl groups significantly enhance its hydrophilicity and coordination capability. It demonstrates outstanding performance in CO2 capture, organic catalysis, heavy metal ion adsorption, and controlled drug release. The commercial product KAR-F30-OH guarantees consistent quality and batch-to-batch reproducibility, making it an excellent choice for both research and industrial applications.

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Description

Key Properties & Advantages
UIO-66-(OH)???s performance is driven by its structural design and hydroxyl functionalization:

Exceptional Thermal & Chemical Stability: Maintains structural integrity at temperatures up to 380??C (under inert conditions) and resists degradation in acidic, basic, and organic solvent environments??ideal for harsh operational settings where many MOFs fail.
Ordered Porous Structure: Features a well-defined 3D porous network with a large BET surface area (typically 750?C1100 m2/g) and uniform pore size (~1.0 nm), enabling efficient molecular diffusion and high adsorption capacity.
Hydroxyl-Enhanced Surface Reactivity: The -OH groups introduce:
Strong hydrogen-bonding capabilities, improving selectivity for polar molecules (e.g., CO?, water, alcohols).
Lewis acid/base sites, enabling participation in acid-catalyzed or base-catalyzed reactions.
Chelation with metal ions, facilitating functionalization for targeted catalysis or sensing.
Tailored Selectivity: The density of hydroxyl groups can be controlled during synthesis, allowing customization of interactions with target molecules (e.g., adjusting affinity for specific gases or pollutants).
Batch-to-Batch Consistency: KAR-F30-(OH)? ensures minimal variation in key properties (surface area, porosity, functional group density), a critical advantage for scaling from lab research to industrial applications.
Applications
Gas Storage & Separation
Selective Gas Adsorption: Hydroxyl groups enhance affinity for polar gases like CO? and H?, making it effective for:
Carbon capture from flue gases or industrial emissions (via selective CO? adsorption).
Hydrogen purification and storage (supporting clean energy technologies).
Mixed gas separation (e.g., CO?/CH? in natural gas upgrading, H?/CO? in syngas processing).
Liquid-Phase Adsorption
Pollutant Removal: Its porous structure and hydroxyl-mediated interactions enable efficient adsorption of liquid-phase contaminants, including:
Organic pollutants (e.g., phenols, dyes, pharmaceuticals) via hydrogen bonding and hydrophobic interactions.
Heavy metal ions (e.g., Cr3?, Cu2?) through chelation with -OH groups, supporting wastewater purification.
Catalytic Applications
Acid/Base Catalysis: Hydroxyl groups act as active sites for acid-catalyzed reactions (e.g., esterification, dehydration) and base-mediated processes (e.g., aldol condensation), leveraging their amphoteric nature.
Catalyst Support: Serves as a stable platform for anchoring metal nanoparticles (e.g., Pt, Ru) or metal oxides, with -OH groups enhancing particle dispersion and catalytic activity in reactions like:
CO? hydrogenation to value-added chemicals (e.g., methanol).
Oxidation of organic compounds (e.g., alcohol oxidation to aldehydes).
Technical Specifications
Parameter Details
CAS Number 1356031-63-4
Chemical Composition Zirconium clusters linked by dihydroxyl terephthalate ligands (typical formula: Zr?O?(OH)?(bdc-(OH)?)?, where bdc-(OH)? = 2,5-dihydroxyterephthalate)
Appearance Off-white to light beige fine powder
Purity ??95% (commercial grade)
BET Surface Area 750?C1100 m2/g
Pore Size ~1.0 nm (uniform distribution)
Thermal Stability Up to 380??C (inert atmosphere)
Quality Assurance
Each batch of KAR-F30-(OH)? undergoes rigorous characterization to ensure reliability:

X-ray diffraction (XRD) confirms structural integrity and phase purity.
Nitrogen adsorption-desorption isotherms verify surface area and pore size distribution.
Thermal gravimetric analysis (TGA) validates thermal stability.
Fourier-transform infrared (FTIR) spectroscopy confirms hydroxyl group presence and density.

A certificate of analysis (CoA) is provided with each order, documenting batch-specific performance metrics.
Handling & Storage
Handling: Use in a well-ventilated area; wear gloves and safety glasses to prevent inhalation of fine powder.
Storage: Store in an airtight, moisture-resistant container at room temperature. Protect from strong oxidizers. Shelf life is ??12 months under proper storage conditions.
Packaging Options
Available in 1g, 5g, 10g, 50g, and bulk quantities. Packaged in vacuum-sealed, moisture-barrier containers to preserve porosity and hydroxyl group activity during shipping and storage.
Why Choose UIO-66-(OH)? (KAR-F30-(OH)?)?
UIO-66-(OH)? bridges stability and selectivity, offering a unique combination of durability and hydroxyl-mediated functionality. Whether you??re developing gas separation systems, pollutant removal technologies, or catalytic processes, KAR-F30-(OH)? delivers consistent performance to support advancements from lab research to industrial scale.

Contact our technical team for customization options (e.g., hydroxyl group density adjustment), bulk pricing, or application-specific data.

For research and industrial use only. Not intended for medical or diagnostic applications.